双金属改性分子筛催化剂在柴油机NH3-SCR反应中的协同效应研究的中期报告.docxVIP

双金属改性分子筛催化剂在柴油机NH3-SCR反应中的协同效应研究的中期报告 摘要： 本研究旨在研究双金属改性分子筛催化剂在柴油机尿素选择性催化还原（NH3-SCR）反应中的协同效应。通过差热分析（DSC）、氮气吸附-脱附、X射线粉末衍射（XRD）、透射电子显微镜（TEM）等技术对催化剂进行了表征。采用甲醇和醋酸酯法制备不同金属比例的Cu-Fe/MOR和Cu-Fe/BEA催化剂，并探讨了Cu和Fe之间的相互作用对催化剂性能的影响。实验结果表明，Cu-Fe/MOR和Cu-Fe/BEA催化剂均具有较高的NH3-SCR活性，在250-450°C的温度范围内NOx转化率可达到80%以上，其中Cu-Fe/MOR催化剂的性能更佳。同时，与单金属Cu/MOR和Fe/MOR催化剂相比，双金属改性催化剂表现出更高的催化活性和稳定性。这种协同效应可能是由Cu-Fe之间的相互作用、不同金属对催化剂酸性和碱性位置的调整以及活性组分的合理分散等多因素共同作用所致。未来工作将重点研究双金属改性催化剂的反应机理。 关键词：柴油机；NH3-SCR；双金属改性分子筛催化剂；协同效应 Abstract: The aim of this study is to investigate the synergistic effect of bimetallic modified zeolite catalysts in the selective catalytic reduction (SCR) of NOx with NH3 from diesel engines. The catalysts were characterized by differential scanning calorimetry (DSC), nitrogen adsorption-desorption, X-ray powder diffraction (XRD), and transmission electron microscopy (TEM). Cu-Fe/MOR and Cu-Fe/BEA catalysts with different metal ratios were prepared by methanol and acetic ester methods, and the effect of the interaction between Cu and Fe on the catalyst performance was also explored. The experimental results showed that Cu-Fe/MOR and Cu-Fe/BEA catalysts had high NH3-SCR activity, and the NOx conversion rate could reach more than 80% in the temperature range of 250-450°C, in which Cu-Fe/MOR catalyst showed better performance. Moreover, the bimetallic-modified catalysts exhibited higher catalytic activity and stability compared with the monometallic Cu/MOR and Fe/MOR catalysts. This synergistic effect may be attributed to the interaction between Cu and Fe, the adjustment of the acidity and basicity of the catalyst by different metals, and the reasonable dispersion of the active components. Future work will focus on the reaction mechanism of the bimetallic modified catalysts. Keywords: diesel engine; NH3-SCR; bimetallic-modified zeolite catalyst; synergistic effect