(9613)--降黏型减水剂的合成及其对高石粉机制砂混凝土性能的影响.pdfVIP

降黏型减水剂的合成及其对高石粉机制砂 混凝土性能的影响 摘 要： 以TPEG-1800、AA、AM、丙烯酸乙酯为主要原料，共聚合成降黏型减水剂UC-01，对其进行了IR 结构表征，同时与普通结构 的UC-100 减水剂进行GPC、溶液表面张力、稳泡能力、水泥水化温升、水泥净浆流变性能、不同比例高石粉含量机制砂混凝土性 能对比。结果表明降黏型减水剂UC-01 具有较低的相对分子质量和较窄的相对分子质量分布；配制的溶液表面张力更低、稳泡效果更 好；能降低水泥水化放热温升；有效的降低水泥净浆的黏度；在不同比例高石粉含量机制砂中都能更好的降低混凝土的黏度和收缩。 关键词： 降黏型减水剂；表面张力；水化热；流变性能；干缩 中图分类号： TU528.042.2 文献标志码： A 文章编号： 1002-3550 （2020）06-0061-04 DING Qingj un a，b ，CHEN Jian a，b （a.State Key Laboratory of Silicate Materials for Architecture ； b.School of Materials Science and Engineering ，Wuhan University of Technology，Wuhan 430070 ，China） Abstract:Viscosity poly carboxylic acid water reducing agent （UC-01）was synthesized by TPEG-1800 ，acrylic acid ，acrylamide and ethyl acrylate.The structure of UC-01 was characterized by IR.Analyses and experiments ，including GPC ，solution surface tension，foam stabilization，temperature rise caused by cement hydration ，cement paste fluidity，and concrete properties with different content high stone powder were done to make comparison between UC-01 and normal water-reducing agent.The results show that the viscosity-reducing type water reducing agent UC-01 has smaller molecular weight and wider molecular weight distribution.The solution of UC-01 has lower surface tension and better foam stabilization effect.UC-01 can reduce the temperature rise caused by cement hydration heat ，it also can reduce the viscosity of cement paste effectively.UC-01 appears better capacity to reduce the viscosity and shrinkage of different concretes ， which were made by manufactured sands with different proportion high stone powder. Keywords:viscosity water reducing agent ；surface tension；hydration heat ；rheologic property ；drying shrinkage 量带来混凝土的需水量增大，混凝土发