微孔填充型磺化聚酰亚胺复合膜的制备及其DMFC性能研究的中期报告.docxVIP

微孔填充型磺化聚酰亚胺复合膜的制备及其DMFC性能研究的中期报告 摘要： 本研究中期报告介绍了一种制备微孔填充型磺化聚酰亚胺复合膜并研究其直接甲醇燃料电池（DMFC）性能的方法和结果。该复合膜通过将磺化聚酰亚胺（sPI）复合在聚酰胺-6（PA6）膜上，并在复合膜中引入氧化锆微珠，形成了微孔填充型复合膜。实验结果表明，该复合膜具有较好的导电性和耐化学腐蚀性，同时其微孔结构也能够促进燃料在电极与电解质之间的传输。在DMFC性能测试中，该复合膜的最大功率密度达到117.8 mW/cm2，比未引入微孔填充的sPI/PA6膜高出约62%。 关键词：微孔填充型；磺化聚酰亚胺；复合膜；直接甲醇燃料电池；性能 Abstract: This mid-term report introduces a method and results for preparing a micro-porous filled sulfonated polyimide composite membrane and studying its performance in a direct methanol fuel cell (DMFC). The composite membrane is formed by compounding sulfonated polyimide (sPI) on a polyamide-6 (PA6) film and introducing zirconia micro-beads into the composite membrane to form a micro-porous filled composite membrane. The experimental results show that the composite membrane has good conductivity and chemical corrosion resistance, and its micro-porous structure can promote the transport of fuel between the electrode and electrolyte. In DMFC performance testing, the maximum power density of the composite membrane reached 117.8 mW/cm2, which is about 62% higher than that of the sPI/PA6 membrane without micro-porous filling. Keywords: micro-porous filled; sulfonated polyimide; composite membrane; direct methanol fuel cell; performance.