马来酸酐固相接枝ABS树脂及在合金中的应用的中期报告.docxVIP

马来酸酐固相接枝ABS树脂及在合金中的应用的中期报告 摘要： 本文研究了马来酸酐固相接枝ABS树脂的制备及其在ABS/PC合金中的应用。采用过氧化苯甲酰及十二烷基硫酸钠作引发剂，在不同反应温度和时间下制备了一系列接枝度为0.5%~2.5%的接枝ABS树脂。对接枝ABS树脂的结构进行了表征，确认其已经成功接枝马来酸酐。将接枝ABS树脂与PC混合，制备了一系列ABS/PC合金，并对其力学性能、热稳定性和耐冲击性进行了测试。结果表明，随着接枝度的增加，ABS/PC合金的力学性能和热稳定性均得到了明显提高，但耐冲击性则略有下降。特别地，当接枝度为1.5%时，ABS/PC合金的力学性能和热稳定性均较好，而且耐冲击性也处于较高水平。 关键词：马来酸酐；固相接枝；ABS树脂；ABS/PC合金 Abstract： Phthalic anhydride-grafted ABS resin was prepared by the solid-phase grafting method and applied to ABS/PC alloy. A series of graft copolymers with grafting degree ranging from 0.5% to 2.5% were synthesized by using benzoyl peroxide and sodium dodecyl sulfate as initiators at different reaction temperatures and times. The structure of the grafted ABS resin was characterized, and it was confirmed that phthalic anhydride was successfully grafted onto the ABS backbone. The ABS/PC alloys were prepared by mixing the grafted ABS resin with PC, and their mechanical properties, thermal stability, and impact resistance were tested. The results showed that with the increase of grafting degree, the mechanical properties and thermal stability of the ABS/PC alloys were significantly improved, while the impact resistance was slightly decreased. Especially, when the grafting degree was 1.5%, the ABS/PC alloy showed good mechanical properties, thermal stability, and impact resistance. Keywords: phthalic anhydride; solid-phase grafting; ABS resin; ABS/PC alloy