高性能硫化物基全固态锂电池设计：从实验室到实用化.pdfVIP

物 理 化 学 学 报 Acta Phys. -Chim. Sin. 2023, 39 (8), 2301027 (1 of 25) [Review] doi: 10.3866/PKU.WHXB202301027 Designing High-Performance Sulfide-Based All-Solid-State Lithium Batteries: From Laboratory to Practical Application , Yuankai Liu 1,2, Tao Yu 1,2, Shaohua Guo 1 2,* , Haoshen Zhou 1,* 1 College of Engineering and Applied Sciences, Nanjing University, Nanjing 210023, China. 2 Shenzhen Research Institute of Nanjing University, Shenzhen 518000, Guangdong Province, China. Abstract: All-solid-state lithium batteries (ASSB) have emerged as key components in energy storage applications owing to their superior safety characteristics and high energy density. The use of sulfide solid electrolytes has considerably promoted the development of all-solid-state lithium batteries because of advantages such as a high ionic conductivity, formability, and good interface compatibility with electrodes. In this review, we first discuss the issues hindering the use of sulfide-based all-solid-state lithium batteries, focusing on aspects related to the cathode/electrolyte interface, sulfide solid electrolytes, and the anode/electrolyte interface. At the cathode/electrolyte interface, interfacial side reactions inherently occur due to the narrow electrochemical window of sulfide electrolytes when used with high-voltage cathode materials, which degrades the battery performance. In addition, owing to the chemical potential difference between cathode materials and sulfide solid electrolytes, the space-charge layer generated due to the formation of a lithium depletion layer is also detrimental to the cell performance. To overcome these difficulties, iner