四氯苯酚降解加膜.pdf

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ScienceinChinaSeriesB:Chemistry

Springer

Comparativestudyonelectrochemicaldegradationof

4-chlorophenolbydifferentPd/Cgasdiffusion

electrodes

WANGHuiWANGJianLong†

LaboratoryofEnvironmentalTechnology,INET,TsinghuaUniversity,Beijing100084,China

Pd/CcatalystusedforthePd/Cgasdiffusioncathodeswaspreparedbyhydrogenreductionmethod

andformaldehydereductionmethod,andcharacterizedbyX-raydiffraction(XRD),transmissionelec-

trodemicrocopy(TEM),X-rayphotoelectronspectroscopy(XPS),andcyclicvoltammetry(CV)tech-

niques.Theelectrochemicaldegradationof4-chlorophenolwasinvestigatedinthediaphragmelec-

trolysissystem,aeratingfirstlywithhydrogengasthenwithair,usingthreedifferentkindsofgasdif-

fusioncathode.Theresultsindicatedthattheself-madePd/Cgasdiffusioncathodecannotonlyre-

ductivelydechlorinate4-chlorophenolsbyaeratinghydrogengas,butalsoacceleratethetwo-electron

reductionofOtohydrogenperoxide(HO)byaeratingair.Therefore,theremovalefficiencyof

222

4-chlorophenolbyusingPd/CgasdiffusioncathodeisbetterthanthatoftheC/PTFEgasdiffusion

cathode(nocatalyst).ThecatalyticactivityofPd/Ccatalystpreparedbyhydrogenreductionmethodis

higherthanthatpreparedbyformaldehydereductionmethod.ThestabilityofthePd/Cgasdiffusion

cathodesisgood.Therefore,boththeremovalefficiencyandthedechlorinationdegreeof

4-chlorophenolreachedabout100%after60min,andtheremovalefficiencyof4-chlorophenolinterms

ofchemicaloxygendemand(COD)inthecathodiccompartmentreached87.4%after120min.

electrochemicaloxidation,gasdiffusioncathode,Pd/Cca

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