碳布负载PTFE_碳黑复合电极还原氧气产过氧化氢.pdfVIP

2024年第50卷第2期工业安全与环保

February2024IndustrialSafetyandEnvironmentalProtection89.

环境管理与咨询

碳布负载PTFE/碳黑复合电极还原氧气产过氧化氢

季立亚赵天贺朱兆连黄琪媛韩欣雨高燕

（南京工业大学环境科学与工程学院，江苏南京211816）

摘要以导电碳布为基体，负载PTFE/碳黑涂层制备复合电极。考察了碳黑类型、碳黑添加量对碳布

负载PTFE/碳黑复合电极产H,O2性能的影响，同时考察了电极的重复使用稳定性。结果表明：在粘结剂PTFE

浓度为20%、电流密度为10mA/cm²、氧气流量为200mL/min、乙炔黑添加量为0.035g时制备的复合电极产

H0z性能最佳，180min内H,0z最高产量达到25.2mg/(L·cm），比未添加乙炔黑的电极提高了31.3%。复

合电极180min内产H.Oz的电流效率为47.2%，能耗为15.7kW·h(每kgHO）。碳布负载PTFE/碳黑复合

电极重复使用8次后H.02最高产量仅下降了8.4%，体现出较好的重复使用稳定性。

关键词碳布PTFE碳黑过氧化氢氧还原

ProductionofhydrogenperoxidebycarbonclothsupportedPTFE/carbonblackcompositeelectrode

JILiyaZHAOTianheZHUZhaolianHUANGQiyuanHANXinyuGAOYan

(SchoolofEnvironmentalScienceandEngineering,NanjingTechUniversity,NanjingJiangsu211816,China)

AbstractThecompositeelectrodewaspreparedbyloadingPTFE/carbonblackcoatingonconductivecarboncloth

substrate.TheeffectsofcarbonblacktypeandcarbonblackcontentonH,O2productionperformanceofcarboncloth

supportedPTFE/carbonblackcompositeelectrodewereinvestigated,andthereusabilityofthecompositeelectrode

wasalsoinvestigated.TheresultsshowedthatthecompositeelectrodecouldachievethebestH,O2productionperform-

anceunderthefollowingexperimentalconditions:theconcentrationofPTFEwas20%,thecurrentdensitywas10

mA/cm²,theoxygenflowratewas200mL/min,andtheacetyleneblackadditionamountwas0.035g.Thehighest

HO,yieldcouldreach25.2mg/(L:cm)within180min,whichwas31.3%higherthanthatoftheelectrodewithout

acetyleneblack.ThecurrentefficiencyofthecompositeelectrodeforH,O2productionin180minwas47.2%,andthe

energyconsumptionwas15.7(kW·h)kg-H,O2.ThemaximumHO,