LC-MS常见污染物质列表.docx

由Dr.JohnLangley,UniversityofSouthampton研究得出如果有些峰一直都洗不掉，不妨找找看，在list里面有没有ContaminationPeaks-PositiveIonES

m/z Ion Compound

42 (M+H)+ acetonitrile

59 (M+NH4)+ acetonitrile

(M+Na)+ acetonitrile

(2M+H)+ methanol

79 (M+H)+ DMSO

83 (2M+H)+ acetonitrile

85 (M+H)+ d6-DMSO

(M+Na)+ DMSO

(M+H)+ triethylamine(TEA)

104/106 (M+Cu)+ acetonitrile

105 (2M+Na)+ acetonitrile

120 (M+Na+CH3CN)+ DMSO

(M+H)+ Tris

(M+H)+ dimethylaminopyridine(DMAP)

130 (M+H)+ diisopropylethylamine(DIPEA)

144 (M+H)+ tripropylamine(TPA)145/147 (2M+Cu)+ acetonitrile

146 (3M+Na)+ acetonitrile

150 (M+H)+ phenyldiethylamine

153 (M+H)+ 1,8-diazabicyclo[5.4.0]undec-7-ene(DBU)

157 (2M+H)+ DMSO

159 (M+Na)+ sodiumtrifluoroacetate

169 (2M+H)+ d6-DMSO

179 (2M+Na)+ DMSO

186 (M+H)+ tributylamine

214 (M+H)+ unidentifiedcontaminant,mayberelatedtomethanol

225 (M+H)+ dicyclohexylurea(DCU)239/241 [(M.HCl)2-Cl]+ triethylamine

M+ tetrabutylammonium(C4H9)4N+

M+ tritylcation

257 (3M+H)+ DMSO

273 M+ monomethoxytritylcation(MMT)

279 (M+H)+ dibutylphthalate(plasticiser)

301 (M+Na)+ dibutylphthalate(plasticiser)

317 (M+K)+ dibutylphthalate(plasticiser)

338 (M+H)+ erucamide

360 (M+Na)+ erucamide

391 (M+H)+ diisooctylphthalate(plasticiser)

413 (M+Na)+

425 (M+Na)+

diisooctylphthalate(plasticiser)unidentifiedcontaminant(plasticiser)

429

(M+K)+ diisooctylphthalate(plasticiser)

449

(2M+H)+ dicyclohexylurea(DCU)

454

(M+Na+CH3CN)+ diisooctylphthalate(plasticiser)

798

(2M+NH4)+ diisooctylphthalate(plasticiser)

803

(2M+Na)+ diisooctylphthalate(plasticiser)