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_喷雾干燥法制备偏钨酸铵微球时的形貌与粒度.pdf

_喷雾干燥法制备偏钨酸铵微球时的形貌与粒度.pdf

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221No.1Vol.22

20082JournalofChemicalEngineeringofChineseUniversitiesFeb.2008

1003-9015(2008)01-0122-06

,,,,

(

,310032)

(AMT)(WC)WC

AMT

AMT

(d50)2.26µm

-WC

TQ028.672A

MorphologyandSizeofAmmoniumMetatungstateMicrosphere

PreparedbySprayDryingMethod

SHENGJiang-feng,MAChun-an,ZHANGCheng,LIGuo-hua,ZHANGWei-min

(StateKeyLaboratoryBreedingBaseforGreenChemistrySynthesisTechnology,ResearchCenterofNano

ScienceandTechnology,CollegeofChemicalEngineeringandMaterialsScience,ZhejiangUniversityof

Technology,Hangzhou310032,China)

Abstract:Ammoniummetatungstate(AMT)isusuallyusedasoneoftheprecursorsoftungstencarbide(WC)

catalyst,andthepropertiesofAMTprecursoraffectthemorphologyandsizedistributionofWCmicrosphere,

whichhaveafinallyeffectonthecatalystactivity.Inthiswork,themechanismsofairflowandcentrifugalspray

dryingmethodswereintroduced,thentheAMTmicrosphereshavingdifferentmorphologieswerepreparedby

usingthesetwokindsofspraydryingmethods,andthemorphologyandsizeofthemicrospherespreparedwere

studied.Theresultsshowthatthemorphologyofthepowderpreparedbycentrifugalspraydryingissolid

sphere,anditisdifferentfromthatofthepowderpreparedbyairflowspraydrying,whichishollowsphere.For

theairflowspraydryingmethodused,theeffectsofsolutionconcentration,feedrateandsurfactantonthe

particlesizeofproductswereinvestigated.Itwasfoundthatthesolutionconcentr

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