气体的临界常数及在水中的溶解度.docxVIP

气体的临界常数及在水中的溶解度

CriticalConstantsandtheAquaticSolubilitiesofGases

单质气体的临界常数

CriticalConstantsofElementarySubstanceGases

序号(No.)

分子式

(Molecularformula)

临界温度

(Criticaltemperature)?Tc/℃

临界压力

(Criticalpressure)

pc/(106Pa)

临界密度

(Criticaldensity)

ρc/(g/ml)

1

Ar

-122.4

4.8734

0.533

2

As

530.0

34.651

-

3

Br2

311.0

10.334

1.26

4

Cs

1806.0

-

0.44

5

Cl2

144.0

7.7003

0.573

6

D2

-234.9

1.6515

0.669

7

F2

-128.85

5.2149

0.574

8

H2

-240.17

1.2928

0.0314

9

He

-267.96

0.22695

0.0698

10

3He

-269.84

0.11449

0.0414

11

Hg

1462.0

18.946

-

12

I2

546.0

-

1.64

13

K

1950.0

16.211

0.187

14

Kr

-63.8

5.5016

0.919

15

Li

2950.0

68.897

0.105

16

N2

-147.0

3.3942

0.313

17

Na

2300.0

35.462

0.198

18

Ne

-228.75

2.7559

0.484

19

O2

-118.57

5.0426

0.436

20

O3

-12.1

5.5726

0.54

21

P

721.0

-

-

22

Ra

104.0

6.2818

-

23

Rb

1832.0

-

0.34

24

S

1041.0

11.753

-

25

Si

-3.5

4.8430

-

26

Xe

16.583

5.8400

1.11

无机化合物气体的临界常数

CriticalConstantsofInorganicCompoundGases

分子式(Molecularformula)

临界温度(Criticaltemperature)Tc/℃

临界压力(Criticalpressure)

pc/(106Pa)

临界密度(Criticaldensity)

ρc/(g/ml)

分子式(Molecularformula)

临界温度

(Criticaltemperature)

Tc/℃

临界压力(Criticalpressure)

pc/(106Pa)

临界密度(Criticaldensity)

ρc/(g/ml)

空气(Air)

-140.6

3.7691

0.313

HfCl4

450.0

5.7752

1.05

AlBr3

356.0

2.6343

0.510

HgCl2

700.0

-

1.56

AlCl3

490.0

2.8876

0.860

NF3

-39.2

4.5290

-

AsCl3

318.0

-

0.720

NH3

132.4

11.276

0.235

BBr3

300.0

-

0.90

NO

-93.0

6.4844

0.52

BCl3

178.8

38.704

-

NO2

158.0

10.132

0.55

BF3

-12.3

4.9849

-

N2F4

36.2

3.7488

-

B2H6

16.6

4.0528

-

N2H4

380.0

14.691

-

BiCl3

906.0

11.955

1.21

N2O

36.41

7.2443

0.452

(CN)2

127

5.9778

-

PH3

51.6

6.5351

-

CO

-140.24

3.4985

0.301

SF6

45.54

3.7589

0.736

CO2

31.0

7.3760

0.468

SO2

157.6

7.8837

0.525

COS

102.0

5.8765

0.44

SO3

217.8

8.2069

0.63

GeCl4

279.0

3.8501

0.65

SbCl3

521.0

-

0.84

HBr

90.0

8.5514

-

SiClF3

34.5

3.4651

-

HCl

51.5

8.3082

0.45

SiCl2F2

95.8

3.4955

-

HCN

183.6

5.3902

0.195

SiCl3F

165.3

3.5765

-

HI

150.8

8.3082

-

SiCl4

234.0

3.7488

0.521

HF

188.0

6.4844

0.29

SiF4

-14.1

3.71