旋锻对粉末冶金钒基储氢合金性能的影响.pdfVIP

HotWorkingTechnology2020,Vol.49,No.21

旋锻对粉末冶金机基储氢合金性能的影响

王明绪I,刘强强2

(1.河南工业职业技术学院，河南南阳473000;2.河南理工大学材料科学与工程学院，河南焦作454000)

摘要：为了改善粉末冶金锐基储氢合金的性能，本文对粉末冶金V3TiNi0.56M基储氢合金进行了旋锻，并进行了

合金试样的充放电循环试验、碱液腐蚀试验和显微组织分析。结果表明，与粉末冶金合金试样相比，经过旋锻后的合金

内部晶粒细化，充放电循环20次的放电容量衰减率减小21%,腐蚀电位正移38mVo旋锻可显著改善粉末冶金

VsTiNi。％锐基储氢合金的充放电循环稳定性和耐碱液腐蚀性能。

关键词:VsTiNio.56M基储氢合金；粉末冶金；旋锻；充放电循环稳定性；耐碱液腐蚀性能

DOI:10.14158/j.cnki.1001-3814.

中图分类号：TG316文献标识码:A文章编号:1001-3814(2020)21-0096-03

EffectofRotaryForgingonPropertiesofPowderMetallurgy

Vanadium-basedHydrogenStorageAlloy

WANGMingxu1,LIUQiangqiang2

(1.HenanPolytechnicInstitute,Nanyang473000,China;2.SchoolofMaterialsScienceandEngineering,HenanPolytechnic

University,Jiaozuo454000,China)

Abstract:Inordertoimprovetheperformanceofpowdermetallurgyvanadium-basedhydrogenstoragealloy,the

rotatingforgingofpowdermetallurgyV3TiNio,56vanadium-basedhydrogenstoragealloywascarriedout.Thecharge-discharge

cycletest,alkalicorrosiontestandmicrostructureanalysisofthealloysampleswerecarriedout.Theresultsshowthat

comparedwiththatofthepowdermetallurgyalloysample,thegrainofthealloyaftertherotaryforgingisrefined,the

dischargecapacitydecayrateafter20timescharge-dischargecyclesisdecreasedby21%,andthecorrosionpotentialis

positivelyshiftedby38mV.Rotatingforgingcansignificantlyimprovethecharge-dischargecyclestabilityandalkali

corrosionresistanceofpowdermetallurgyV3TiNi0.56vanadium-basedhydrogenstoragealloy.

Keywords：V3TiNi056vanadium-basedhydrogenstoragealloy;powdermetallurgy;rotaryforging;chargeanddischarge

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