聚丙烯酰胺共混水溶液体系相互作用及其共聚物增黏应用.pdfVIP

浙江大学硕士学位论文ABSTRACT

ABSTRACT

Reversiblechaintransfer

addition-fragmentationpolymerizationmethod(RAFT)is

usedinradicalwith

aqueouspolymerizationpreparedS，F—bis(a，at_dimethyl·a-aceticacid)-

trithiocarbonateaRAFT

aswater-solubleimidazoline

reagent，azobisisopropyl

KPSasthe

hydrochloride(VA044)orinitiator，and

ammoniumchloride

dimethylbenzyl(AODBAC)，

otherto

monomersnarrow

chloride(DMC)andacrylamide

trimethylammoniumsynthesize

distributionthesisdiscussestheinfluencestoofthe

homopolymers．Theperformance

frominitialmonomerrawmaterialratioofthe

polymerizationproduceconcentration，the

monomerandinitiatortotheRAFTcontrol

reagent，andpolymerizationtemperature．Precise

ofrelativemolecularmassofwater-solubleisbrominationtitration

polymerrealized．Using

1

basedondoublebondandHNMRdetectionmethodsthatinthe

addition，GPCproved

controllable／activefreeradicalsinthemonomer

acrylamide—basedaqueoussolution，the

reactionconversionrateoftheismolecularmassis

polymerizedproducthigh，relative

similartothedistributionindexissmallwith

value，molecular

designweightgood

anfor

uniformity．Itidealmateria