制氢微反应器的波纹基板与泡沫铜的连接工艺及装配结构研究.pdfVIP

(4)针对层叠装配后的重整制氢微反应器进行性能测试，包括反应器的气密性与制氢

性能。首先，基于之前确定的密封结构，压制出波纹基板，并在相应的螺栓孔和气孔位置

处打孔，随后钎焊连接波纹基板与泡沫铜，接着进行催化剂悬浊液的制备和催化剂涂覆，

最终完成反应器的层叠装配。其次，基于容积补偿原理，设计并搭建了气密性测试系统，

结果显示，在2~10kPa的工作气压范围内，45000N的装配压力下，反应器能够达到美国

压力容器委员会针对法兰连接系统提出的T3(紧密)紧密度等级，且串气量一直维持在更低

的水平。最后，搭建微反应器的制氢性能测试平台，开展反应器的制氢性能测试，验证了

本文工作的有效性。

关键词：重整制氢反应器；钎焊工艺；泡沫铜；波纹基板；层叠装配；制氢

ABSTRACT

Cleanandefficienthydrogenenergyapplicationsarebecomingmoreandmoreextensivein

ourlives.However,therearestillproblemsofpoorsafetyandlowefficiencyinhydrogenstorage

andtransportation.Theon-sitehydrogenproductiontechnologycanavoidtheseproblemswell,

anditisahotspotinhydrogenenergyresearch.ThisworkwassupportedbyNaturalScience

FoundationofChinaunderGrantU1809220.Theconnectionandassemblyproblemsofreforming

hydrogenproductionmicroreactorwithcopperfoam-corrugatedsubstratestructurewerestudied.

Thereliableconnectionbetweencorrugatedsubstrateandcopperfoamwasrealizedthrough

brazingprocess.TheABAQUSnumericalassemblymodelwasestablishedtooptimizethe

structureofsealinggasket.Finally,thesealingperformanceandhydrogenproductionperformance

ofthemicroreactorweretestedbyexperiments.Themainresearchcontentsofthispaperareas

follows:

(1)Accordingtothestructuralcharacteristics,workingconditionsandconnection

requirementsofcorrugatedsubstrateandcopperfoam,thebrazingmethodinatmospherefurnace

wasselected,andAgCuZnSnsolderwasselectedforbrazingconnection.Inordertodetermine

theappropriatebrazingprocessparameters,thebrazingexperimentsofcopperandstainlesssteel

substrateinanatmospherefurnaceweredesigned.Thejointshearstrengthofthebrazingsamples

obtainedunderdifferentjointgaps,brazingtemperaturesandholdingtimeweretested,andthe

a