电厂锅炉水冷壁管高温抗氧化涂层的制备及性能研究.docxVIP

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圆园23年第4期网址：电邮：hrbengineer@163.com

电厂锅炉水冷壁管高温抗氧化涂层的制备及性能研究

王彬彬，孙帅辉，张若男

（中国矿业大学（北京）机电与信息工程学院，北京100083）

摘要：电厂锅炉水冷壁的高温氧化问题严重地影响了电厂的安全性和经济性，为了解决该问题，文中采用热化学反应法制备了适用于锅炉水冷壁管的陶瓷涂层，以高温抗氧化性为主要指标，对涂层的各项性能进行评价。结果表明：在800℃温度下，涂层单位面积氧化增重为0.83mg/cm2，涂层结合力为54.6N，可经受18次循环空冷。制备的陶瓷涂层的氧化增重曲线符合抛物线型，氧化活化能为175.82kJ/mol，抗氧化性能良好，有效地降低了电厂锅炉水冷壁的高温氧化速率，延长了其使用寿命。

关键词：水冷壁管；陶瓷涂层；氧化动力学；热化学反应法

中图分类号:TG174.44 文献标志码:粤 文章编号：员园园圆原圆猿猿猿（圆园23）04原园055原园4

PreparationandPropertiesofHighTemperatureOxidationResistantCoatingUsedinWaterWallTubeofBoilerinPowerPlant

WANGBinbin,SUNShuaihui,ZHANGRuonan(SchoolofMechanicalElectronicInformationEngineering,ChinaUniversityofMiningTechnology(Beijing),Beijing100083,China)Abstract:Thehightemperatureoxidationproblemofboilerwaterwallinpowerplantseriouslyaffectsthesafetyandeconomyofthepowerplant.Inordertosolvethisproblem,aceramiccoatingsuitableforboilerwaterwalltubeispreparedbythermochemicalreactionmethod.Asthemainindex,thepropertiesofthecoatingareevaluated.Theresultsshowthatat800益,theoxidationweightgainperunitareais0.83mg/cm2,thecoatingadhesionis54.6N,anditcanwithstand18cyclesofaircooling.Theoxidationweightgaincurveo