储氢材料04-hydrogen storage materials.pptVIP

The electrochemical properties of MA Mg-Ni based binary alloys* 4.2 Amorphous Mg-Ni based alloys 2) MA- (Mg2Ni + Ni) －C. Iwakura of Japan Ni/Mg2Ni ratio － properties 4.2 Amorphous Mg-Ni based alloys As ↑Ni/Mg2Ni ratio, Cmax↑ As Ni/Mg2Ni ratio=2/1, Cmax= 830 mAh/g.(Mg2Ni) 3) MA- Mg2Ni + C (graphite) Mg2Ni / C ratio － properties As Mg2Ni / C ratio=5/1, Cmax= 510 mAh/g, degradation rate↓. 4.2 Amorphous Mg-Ni based alloys The amount of absorbed hydrogen for MgNi alloy, MgNi–graphite composite and MgNi–graphite mixture at 30℃. The discharge capacities of Mg2Ni - 20 wt.% graphite composite ball-milled for different time. 4) MA- Mg-Ni-M alloys MA- MgNi0.9M0.1 (M=Ti, Zn, Mn, Cu, Fe, Co, Zr, W, Cr, Se, Sb, C) Ti, Zn－Cmax↑; 4.2 Amorphous Mg-Ni based alloys Ti, Zn, Zr, Se－degradation rate↓, R9 cycle↑; Other－Cmax↓, degradation rate↑. The electrochemical properties of amorphous MgNi0.9M0.1 alloys* 4.2 Amorphous Mg-Ni based alloys 5) MA- Mg-M-Ni alloys MA- Mg0.9M0.1Ni (M=Ni, Ti, Zr, Co, Si) 4.2 Amorphous Mg-Ni based alloys The XRD patterns of amorphous Mg0.9M0.1Ni (M=Ni, Ti, Zr, Co, Si) alloys (a) MgNi; (b) Mg0.9Ni1.1; (c) Mg0.9Zr0.1Ni; (d) Mg0.9Ti0.1Ni; (e) Mg0.9Co0.1Ni; (f) Mg0.9Si0.1Ni Tel: 0571- 8795 1152 Email: lxchen@zju.edu.cn Laboratory of Hydrogen Storage Materials Institute of Metallic Materials Zhejiang University Hydrogen Storage Materials Dr. Li-xin Chen Magnesium Based Hydrogen Storage Alloys Lecture III I . Introduction 1.1 Advantage High capacity (MgH2: 7.6 wt%, Mg2NiH4: 3.6 wt% ) The hydrogen storage capacities of some HSAs Low cost 1.2 Disadvantage Poor kinetics－low hydrogen absorption rate and desorption rate I . Introduction Very stable hydride Easily corrode in 6M KOH electrolyte － only 20~30 cycles life 2.1 Reaction Ⅱ. Mg - H system High hydriding/dehydriding temperature Low hydrogen absorption/desorption rate 2) The diffusivity of H in Mg-oxide film is