利用焦化工艺处理废塑料2kg焦炉实验研究.pdfVIP

2007 中国钢铁年会论文集 利用焦化工艺处理废塑料 2kg 焦炉实验研究 ——焦油 GC-MS 分析 余广炜 1 廖洪强 1 蔡九菊 2 张振国 1 雷 勇 2 赵 鹏 1 何亚斌 1* （1. 首钢环保产业事业部，北京 100041 ； 2. 东北大学国家环保生态工业重点实验室，沈阳 110004 ） 摘 要 本文利用GC-MS 联用仪考察了添加废塑料与首钢炼焦配煤在2kg 焦炉中共焦化所得焦油的分布特征。研 究结果表明：炼焦配煤单独焦化所得焦油以芳香烃和烷烃组分为主，废塑料单独焦化的焦油中则以烷烃和烯烃为主； 添加2%经预处理的废塑料与煤混合共焦化使焦油中的芳香烃以及烯烃比例明显增加，同时，芳香烃与烷烃表现出 明显的“轻质化”。利用焦化工艺处理废塑料有利于得到优质焦油，这对于提高焦油的经济价值有重要意义。 关键词 塑料 煤 焦化 焦油 GC-MS The Experiments of 2kg Coke-oven on Disposal of Waste Plastics by Coking Process ——GC-MS Analysis on Tar Yu Guangwei1 Liao Hongqiang1 Cai Jiuju2 Zhang Zhenguo1 Lei Yong2 Zhao Peng1 He Yabin1 （1. Shougang Environmental Protection Industry Department, Beijing, 100041; 2. State Key Laboratory of Bio-industry, Northeastern University, Shenyang, 110004 ） Abstract By using the GC-MS, characteristics of the tar achieved by co-coking of waste plastics with coal in 2kg coke-oven were investigated. The result showed that tar resulted from coking of coal mostly consisted of alkyls and aromatic compounds. But for waste plastics, they were alkyls and alkenes. Furthermore, the addition of 2wt% of waste plastics pretreated could enhance the yields of alkenes and aromatic compounds in tar, and, at the same time, get the smaller molecules of aromatic compound and alkyl. The traditional of waste plastics with coal would have economic prospect for improving the quality of tar. Key words plastics, coal, coking, tar, GC-MS 煤焦油是炼焦生产的重要化学副产品，其中有些产品是不可能或者不能经济地从石油化工原料中取得。 因此，煤焦油产品在世界化工原料需求中有极其重要地位，其产量基本受钢铁焦化行业决定。90 年代以来， 大量研究者从塑料、合成塑脂、橡胶轮胎等高