碱度对精炼渣脱氧能力的影响.pdfVIP

碱度对精炼渣脱氧能力的影响 1 2 1 11 邓志银 钟保军 高新亮 朱苗勇 （1．东北大学材料与冶金学院，沈阳 110819 ； 2 .邢台钢铁有限责任公司技术中心，邢台 054027 ） 摘 要 采用作用浓度计算模型分析了精炼渣各组元的作用浓度随碱度的变化规律，从理论的角度研究了碱度对精 炼渣脱氧能力、控制镁铝尖晶石及球状夹杂物能力的影响。通过计算与实验得出以下结论：随着碱度的增加，Al2O3 和 SiO2 的作用浓度不断降低，FeO 和MgO 的作用浓度呈现先增加后降低的趋势；精炼渣碱度小于3~4 有利于控 制镁铝尖晶石的生成。碱度越高，生成球状夹杂物的可能性就越大，精炼渣碱度小于2 可以有效地控制球夹杂物的 生成。随着碱度的增加，精炼渣的脱氧能力增加，碱度在4 左右就接近最大脱氧能力。冶炼要求控制D 类夹杂物 的低氧钢，精炼渣碱度宜控制在4 左右。 关键词 脱氧 作用浓度 碱度 夹杂物 Effect of Basicity on Deoxidation Capability of Refining Slag Deng Zhiyin1 Zhong Baojun2 Gao Xinliang1 Zhu Miaoyong1 (1.School of Materials and Metallurgy, Northeastern University, Shenyang, 110819; 2.Technology Center, Xingtai Iron Steel Co., Ltd., Xingtai ,054027) Abstract Mass action concentration calculation model was used to analyze the change principle of mass action concentration of structural unit when basicity varies, and the effect of basicity on deoxidation capability and control of spinel and globular inclusions was investigated theoretically. From the calculation and experiment results, it was found that with the increase of basicity, the mass action concentration of Al O and SiO decreases, while the mass action 2 3 2 concentration of FeO and MgO increases at first and then decreases. Slag basicity less than 3 to 4 would help to control spinel inclusions formation, and higher basicity improves formation of globular inclusions. Slag with basicity less than 2 can effectively control the formation of globular inclusions. Deoxidation capability of slag increases with the increase of basicity, an