磷酸三丁酯（TBP）萃取酸性氯化铜蚀刻液中亚铜离子的研究.docVIP

  磷酸三丁酯（TBP）萃取酸性氯化铜蚀刻液 中亚铜离子的研究 枚芳1，潘涌璋2** 5 10 15 20 25 30 35 40 （1. 暨南大学理工学院环境工程系，广州 510632； 2. 广东省高校水土环境毒害性污染物防治与生物修复重点实验室，广州 510632） 摘要：以磷酸三丁酯(TBP)为萃取剂，磺化煤油为稀释剂，从酸性氯化铜蚀刻废液中萃取亚 铜离子。研究了 TBP 浓度、油水比(O/A)、萃取时间、HCl 浓度、Cl-浓度等参数对 Cu+、Cu2+ 萃取率的影响，实验结果表明 TBP 对亚铜离子具有极高的选择性，以 80%TBP+20%磺化煤 油为萃取剂，油水比 O/A 为 1:1，萃取时间大于等于 2min，HCl 浓度 3.5mol/L 时 TBP 对亚 铜离子的萃取率达到最大值 98.36%，Cl-浓度对萃取率无显著影响。同时通过化学分析法、 斜率法以及紫外光谱法，证实了 CuCl 以 HCuCl2 形式存在于有机相中，HCuCl2 与 TBP 配位 形成二溶剂化合物 HCuCl2·2TBP，从而达到与其他组分分离的目的。 关键词：酸性氯化铜蚀刻废液；磷酸三丁酯；萃取；亚铜离子 中图分类号：X781.1 Study on extraction of cuprous ions from acid cupric chloride etchant waste by tri-butyl phosphate（TBP） MEI Fang1, PAN Yongzhang2 (1. Department of Environmental Engineering, College of Science and Technology,Jinan University, GuangZhou 510632; 2. Key Laboratory of Water/Soil Toxic Pollutants Control and Bioremediation, Department of Education of Guangdong Province, GuangZhou 510632) Abstract: Cuprous ions was extracted from acid cupric chloride etchant waste with tri-butyl phosphate(TBP) as extractant, sulfonated kerosene as diluents. Effect of various process parameters viz. concentration of TBP, O/A, contact time, concentration of hydrochloric acid and chloride ion, etc on extraction rate were studied. Experimental results showed that the extractant TBP diluted in sulfonated kerosene was suitable for the extraction of cuprous ions from acid cupric chloride etchant waste containing both cuprous ions and cupric ions. And when the concentration of TBP and sulfonated kerosene were 80% and 20%, the O/A was 1:1, the contact time reached 2 minutes and the concentration of hydrochloric acid rised to 3.5 mol/L ,it achieved extraction apparatus, and the extraction rate reached the maximum value 98.36%,while the concentration of chloride ion made no difference on extraction rate. In addition, chemical analysis，slope method and UV spectra confirmed that the cuprous ion in solution reacted with HCl to form HCuCl2，and HCuCl2 coordinated with TBP to form HCuCl2·