N2O分解催化剂的制备及表征.pdfVIP

N O分解催化剂的制备及表征 2 摘 要 采用共沉淀法制备了由铁，锰，钴，镍，锌，铜，镧，铈组成的复合型氧化亚 氮分解催化剂，其元素配比为等比例。实验分析了催化剂的催化活性，并对催化剂 进行了比表面积和XRD表征。 实验研究主要分为两个系列，即七组分和四复合催化剂系列催化剂，同时考察 了沉淀剂对催化性能的影响。另外，考察了由几个品牌废电池制备的催化剂样品的 氧化亚氮分解性能。 实验结果表明，不含 Co 的七组分催化剂分解氧化亚氮的性能不理想，说明 Co 元素的催化活性比较高。而由废电池制备的催化剂催化性能普遍不是很理想。 对于四组分复合催化剂系列，当沉淀剂由氨水改成碳酸钠时，沉淀效果明显改善， 所得到的催化剂活性也稍好。 从实验结果可以推断出：催化剂性能好坏主要取决于部分关键组，而沉淀剂的 选择、沉淀时溶液的碱性环境、元素之间的配比、焙烧的温度也是重要因素。 关键词：共沉淀法，催化剂，稀土金属，复合金属氧化物, N O催化分解 2 I - - N O分解催化剂的制备及表征 2 Abstract The coprecipitation method was applied to synthesize the mixed metal oxide catalysts for N O decomposition, which include La, Mn, Co , Ni , Fe , Zn ,Cu and Ce 2 with the unity proportion. The activities and BET, XRD of the catalysts were investigated in the experiment. Two series of catalysts were synthesized in the experiment, one series contained seven metal elements and the other contained four elements. To examine precipitant affected on catalytic activity, different precipitant was considered. In addition, catalysts made from waste batteries were prepared to examine decomposition activity of N2O. The results show that the seven elements catalyst, which didn’t contain Co, had low activity. In other words, Co element had a good active for N O decomposition. 2 Experiment results indicted that catalysts from battery were