年产10万吨焦化苯萃取精馏工艺设计.pdfVIP

年产 10 万吨焦化苯萃取精馏工艺设计 摘 要 本论文对焦化苯萃取精馏制纯苯过程进行工艺设计，采用 DMF (N,N-二甲基 甲酰胺)作为萃取剂来脱除焦化苯中的含硫化合物噻吩，从而达到精制焦化苯的目 的，制备符合工业要求的纯苯和噻吩浓缩物等产品。 设计的工艺过程采用两次萃取精馏和两次溶剂回收的方案。使用 ASPEN 化工 设计软件对该工艺过程进行模拟计算，并进行工艺过程的调优，得到最佳塔板数、 回流比、采出比等。使用 CHEMCAD 化工软件求得各个塔的塔径、塔高等工艺参 数，根据相关资料和各个工艺参数对再沸器、冷凝器和泵等化工设备进行设计、计 算、选型。使用 AUTOCAD 画图软件画出该工艺过程的带控制点的工艺流程图， 并进行经济效益分析，完成整个工艺过程的经济核算。 关键词：焦化苯，噻吩，DMF ，萃取精馏，工艺设计 I 年产 10 万吨焦化苯萃取精馏工艺设计 Abstract In this dissertation, a technologic process design for producing pure benzene by extractive distillation from coke-oven benzene has been designed. We use DMF(N,N-Dimethylformamide)as solvent to eliminate the thiophene from coke-oven benzene, so as to achieve the purpose of purifying coke-oven benzene. We can prepare pure benzene and thiophene that conform to the industrial demands. In this technologic process design, we use extractive distillation for two times and recycle the solvent for two times. We use the chemical software ASPEN to simulate the whole technologic process and adjust the conditions until the products conform to the industrial demands. We use the chemical software CHEMCAD to calculate the parameters of tower diameter, tower height and so on. According to relative date and technologic parameters, we can design, calculate and choose the model for chemical equipments such as reboiler, condenser and pump. The technologic flow chart can be drawn by AUTOCAD. As last, we analyze the economical benefit and finish the economical calculate of the whole process. Key words: