脂肪族缩水甘油醚的合成.pdfVIP

脂肪族缩水甘油醚的合成 脂肪族缩水甘油醚的合成 摘 要 本文主要研究了在脂肪族缩水甘油醚的合成过程中，不同的温度，原料，原料 配比以及脂肪醇的碳链数，立体结构对试验过程和结果的影响，并对反应产物进行 分离提纯，对主要性能指标进行分析测试。 研究表明：在其它条件不变的情况下，在一定范围内升高温度可使产物的环氧 值增加，也可使产物的产率提高，但是，温度过高会使环氧氯丙烷进行自身的醚化 反应，副产物增加，分离困难，产率降低；相对于单醇羟基的原料来说，多羟基的 原料由于羟基数目和空间结构的变化使反应速度有明显的增加，对反应温度的控制 更加困难，并且在反应过程中可能会存在在一个分子上只有部分羟基参与反应的情 况，从而影响反应产物的产率和性能。 关键词：脂肪族缩水甘油醚，环氧值，相转移，环氧氯丙烷 I 脂肪族缩水甘油醚的合成 Synthesis of Aliphatic Ether Wang LeiChao (Dept. Mat. Sci. Tech., Beijing Institute of Petrochemical Technology) Abstract This article has mainly studied that different temperature, different materials, different material proportions and three-dimensional structure and the number of carbon chain of fatty alcohols have done what different for the result and the process for the test. And also we have done separation and purification for the production of the test, then analysis the result of these numbers for the whole test. The study shows: increase the temperatures in a range will improve the epoxy value and the yield of the product, but if the increase of the temperatures beyond the range, the ECH will has polymerization with its own, and so the number and the epoxy value of the product will be impacted. For the stuff with single alcohol hydroxyl, the test of more alcohol hydroxyl will become more difficult just because of the spaces structures of them, and further more some stuff with more alcohol hydroxyls may reacted in its own molecular, so impacts