用具有不同共轭侧基的噻吩-苯并[1,2-b_4,5-b]二噻吩共聚物的合成及光伏性能研究.docVIP

  Synthesis and photovoltaic properties of copolymers based on benzo[1,2-b:4,5-b’]dithiophene and thiophene with different conjugated side groups# 5 10 15 20 Zhaojie Gu1, Peng Tang1, Xinping Liu1, Bin Zhao2, Ping Shen2, Songting Tan1** (1. College of Chemistry, Xiangtan University, Xiangtan, Hunan 411105; 2. Key Laboratory of Environmentally Friendly Chemistry and Applications of Ministry of Education, Xiangtan University, Xiangtan, Hunan 411105) Abstract: Three novel copolymers (PT-ID, PT-DTBT and PT-DTBTID) of benzo[1,2-b:4,5-b’]dithiophene and thiophene with different conjugated side groups (1,3-indanedione (ID), 4,7-dithien-5-yl-2,1,3-benzodiathiazole (DTBT), and DTBT-ID) were synthesized and developed for polymer solar cell applications. The effects of the different conjugated side groups on the thermal, photophysical, electrochemical and photovoltaic properties of these copolymers were investigated. As the length of the conjugated side groups increased, the absorption of the UV-vis region in solution was red-shifted. By changing the different side groups, the energy levels and band gaps of the resulted copolymers were effectively tuned. The three copolymers exhibit deep HOMO energy level and relatively high open-circuit voltage (Voc). Bulk heterojunction solar cells with these copolymers as electron donors and (6,6)-phenyl-C61-butyric acidmethyl ester (PC61BM) as an electron acceptor exhibit power conversion efficiencies of 2.48%, 4.18% and 1.16% for PT-ID, PT-DTBT and PT-DTBTID, respectively. Key words: Polymer solar cells; bulk heterojunction; benzo(1,2-b:4,5-b)dithiophene; dithienylbenzothiadiazole; side chains；1,3-indanedione 0 Introduction Polymer solar cells (PSCs) have attracted considerable attention in recent years due to their 25 30 35 40 potential for low cost, lightweight, and good compatibility with the roll-to-roll process for making ?exible large area devices[1-3]. So far, the most successful polymer solar cells are bulk hete