甲硫氨酸对镁合金在模拟体液中缓蚀作用研究.docVIP

  甲硫氨酸对镁合金在模拟体液中缓蚀作用 研究# 李卫平，王晓芳，刘慧丛，朱立群* 5 10 15 20 25 30 （空天材料与服役教育部重点实验室，北京航空航天大学材料科学与工程学院, 北京 100191） 摘要：镁基材料是一种很有前途的生物可降解的血管支架材料，然而在人体环境中纯镁降解 速度太快，因此，探讨模拟体液中镁基材料的缓蚀过程很有意义。为此，本文采用集气法、 失重法、电化学测试等手段，考察了甲硫氨酸对 AZ91D 镁合金在模拟体液（SBF 溶液）中 腐蚀速率的影响，结果表明，甲硫氨酸可以明显减缓镁合金的腐蚀速率，在 96h 的实验周期 内，其缓蚀效率可以达到 60.96%。扫描电子显微镜（SEM）和能谱仪（EDS）分析其腐蚀 形貌和腐蚀产物的结果表明，甲硫氨酸的特性吸附对镁合金起到缓蚀作用，并且可促进模拟 体液中形成的羟基磷灰石类腐蚀产物在镁合金表面的沉积，进一步减缓腐蚀的发生。 关键词：缓蚀；AZ91D 镁合金；模拟体液；甲硫氨酸 中图分类号：O646 Inhibiting ability of methionine to magnesium alloy in simulated body fluid solution LI Weiping, WANG Xiaofang, LIU Huicong, ZHU Liqun (Key Laboratory of Aerospace Materials and Performance (Ministry of Education), School of Materials Science and Engineering, Beihang University, Beijing 100191, China) Abstract:Magnesium matrix alloy is a kind of promising biodegradable vessel stent material. However, the magnesium’s degradation rate is too fast in human environment. So it’s significant to research the inhibiting progress of magnesium matrix materials in simulation body fluids. Hydrogen collection, weightlessness and electrochemical test were used to investigate the effect of methionine inhibitor on AZ91D magnesium alloys’ corrosion rate in simulation body fluids. Results indicate that methionine obviously slows down the corrosion rate of magnesium alloys. And 0.005mol/L methionine’s anti-corrosion efficiency reaches 60.96% when test specimen are immersed in the solution for 96 hours. Scanning electron microscopy (SEM) and energy dispersion spectrometry (EDS) methods were used to analyse the corrosion morphology and corrosion products. It implies that the specific adsorption of methionine leads to magnesium alloy’s corrosion inhibition. Moreover, methionine promotes the deposition of hydroxyapatite on the surface of magnesium alloy and it hinders the corrosion progress further. 35 Key words: Inhibition; AZ91D magnesium alloy; SBF solution; Methionine  0 引言 镁基支架材料与现在已投入临床使用的各种金属支架相比具有突出的优点：首先，镁及 镁合金比强度和比刚度高、加工性能良好，可满足血管支架的力学性能