硬软煤质量比变化对煤吸附甲烷的影响.docVIP

  硬软煤质量比变化对煤吸附甲烷的影响# 李树刚，赵鹏翔，林海飞，潘宏宇，成连华，魏宗勇* （西安科技大学能源学院，西安 710054） 5 10 15 20 25 30 35 40 45 摘要：在单一煤体吸附甲烷的基础上，选用山西某煤矿进风硬煤和进风软煤，按照不同的质 量比进行分层混合，模拟煤层中软分层。运用 Langmuir 单分子层吸附理论，对硬煤和软煤 处于不同质量比条件下混合煤样吸附甲烷特性的影响进行了实验研究。实验中利用 WY-98B 型瓦斯常数测定仪和 WFC-2 瓦斯放散初速度测定仪，分别对不同质量比的混合煤样在相同压 力不同质量比情况下吸附甲烷气体的等温吸附曲线、吸附常数 a、b 及瓦斯放散初速度ΔP 进行了定性与定量的分析，并得出了吸附量随硬煤软煤质量比变化的关系曲线、吸附常数 a、 b 随硬煤软煤质量比变化的关系式及瓦斯放散初速度ΔP 随硬煤软煤质量比变化的关系式。 分析结果发现在软煤质量和其上部硬煤质量近似相等时，吸附常数 a 及放散初速度ΔP 达到 最大值，吸附常数 b 达到最小值。这一发现充分说明了在这种情况下，煤体对甲烷的吸附量 及其压力均达到最大值，一旦扰动此类煤层，便会形成很大的压力梯度，发生大量的瓦斯涌 出。 关键词：硬软煤质量比；吸附特性；吸附常数；瓦斯放散初速度 中图分类号：TD712.6 Effcet of mass ratio change of hard and soft coal on adsorption of methane LI Shugang, ZHAO Pengxiang, LIN Haifei, PAN Hongyu, CHENG Lianhua, WEI Zongyong (College of Energy Science and Engineering, Xi’an University of Science and Technology, Xi’an 710054) Abstract: In this paper based on the single coal adsorption gas, choose hard coal and soft coal of into-wind trans-monounsaturated in one mine in Shanxi. According to different quality to mix with delamination to simulate the soft coal in coal bed. Experiment on the hard coal and soft coal characteristics of adsorption gas is researched in different quality ratio conditions by using Langmuir single molecule layer absorption theory. WY-98B gas constant mensuration instrument and WFC-2 initial speed of methane emission mensuration instrument were used in experiment, isothermal adsorption curve at the same pressure and the different mass ratio, adsorption constants a, b and initial speed of methane emission ΔP of the different quality of mixed coal samples gives a qualitative and quantitative analysis, and the conclusion that the relationship curves of adsorption quantity with the pressure for change and variation equation of adsorption constants a, b and initial speed of methane emission ΔP with hard coal and soft coal mass ratio. Analysis results is that the quality of soft coal and hard coal on it approximately equal, adsorption constants a and in