水对V2O5 _AC低温催化NH3-SCR反应动力学的影响.docVIP

  水对 V2O5 /AC 低温催化 NH3-SCR 反应动力 学的影响# 杨昆，雷志刚** 5 10 15 20 25 30 35 40 （北京化工大学化学工程学院，北京 100029） 摘要：活性炭担载五氧化二钒催化剂（V2O5/AC）在 393-473K 条件下对 NH3-SCR 反应具有良 好的活性。但当烟气中含有水时其活性会降低。本文首先研究了水对该催化剂下本征动力学 的影响。实验数据分别用机理模型（Eley-Rideal 模型, Langmuir-Hinshelwood 模型和 Mars-van Krevelen 模型）和经验模型（一级反应模型和幂级数模型）进行拟合。结果显示， 无论烟气中是否含有水，反应都遵循 Eley-Rideal 机理而不是 Langmuir-Hinshelwood 或 Mars-van Krevelen 机理；且随着水含量的增加，指前因子减小而活化能增大。最后，将得 到的本征动力学模型参数代入到 3D 结构化反应器的数学模型之中，发现 Eley-Rideal 模型 能更准确的描述反应器性能。 关键词：本征动力学；选择性催化还原；V2O5/AC 催化剂；结构化反应器；数学模型 中图分类号：X701.3 Influence of H2O on Kinetics of Low-Temperature SCR of NO by NH3 over V2O5 /AC Catalyst Yang Kun, Lei Zhigang (College of Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029) Abstract: The AC (activated carbon) supported V2O5 (vanadium pentoxide) (V2O5/AC) catalyst shows high activities for selective catalytic reduction (SCR) of nitrogen oxide (NO) by ammonia (NH3) at 393-473 K after a pre-sulfated step. But the activities decrease obviously when adding H2O to the flue gas. The influence of H2O on intrinsic kinetics for this catalyst was first investigated in the absence of internal and external diffusions in a fixed-bed micro-reactor. Then, both the mechanical (i.e. Eley-Rideal model, Langmuir-Hinshelwood model, and Mars-van Krevelen model) and empirical (i.e. first-order model and power-rate law model) models were applied to correlate the experimental data. The results showed that the SCR of NO by NH3 over V2O5/AC catalyst follows the Eley-Rideal mechanism rather than Langmuir-Hinshelwood or Mars-van Krevelen mechanism whether H2O is contained in the flue gas or not, and the pre-exponential factor decreases and activation energy increases with the increasing amount of H2O. Finally, the intrinsic kinetic models obtained in this work were incorporated into a 3D mathematical model of monolithic reactor, and it was found that the Eley-Rideal model is more suitable for describing the SCR of NO by NH3 in the presence of H