静电纺丝中的电流电压行为.pdfVIP

·28 · 材料导报网刊 2006 年 5 月第 3 期 静电纺丝中的电流电压行为* 顾书英，张春艳，任 杰 （同济大学材料科学与工程学院，纳米与生物高分子研究所，上海 200092） 摘要 静电纺丝是一种使高聚物熔体或溶液在外加静电场作用下形成射流，制备聚合物超细纤维的有效方法。它涉及 到高分子科学、应用物理学、流体力学、电工学、化学工程、材料工程和流变学等。纺丝参数如电场强度、射流所带电荷、 环境湿度等都影响静电纺丝过程。以聚环氧乙烷（PEO ）的静电纺丝为例，研究了静电纺丝过程中环境湿度、溶液浓度、电 解质浓度和流体静压力对纺丝过程中电流和电压关系的影响。研究结果表明：环境湿度对静电纺丝的电流电压行为没有明显 的影响；但是盐的加入对电流电压行为影响很大；当纺丝时液面高度相同时，电流随着电压线性增大。 关键词 静电纺丝 电流 电压 环境湿度 The Behavior of Current and Voltage in Electrospinning GU Shuying，ZHANG Chunyan ，REN Jie (Institute of Nano- and Bio- Polymeric Materials, School of Materials Science and Engineering, Tongji University, Shanghai 200092) Abstract Electrospinning is a simple and efficient technique for the fabrication of nano to micro scale fibers. It is a process involving polymer science, applied physics, fluid mechanics, electrical, mechanical, chemical, material engineering and rheology. In this paper the behavior of the current and voltage in electrospinning of PEO polymer solution is studied. It seems there is no significant influence of humidity on the I-U curves for different solutions. But the addition of NaCl leads greatly change to the characteristics of the current and voltage. The current increases linearly with voltage for different solutions at different humidity when the height of the electrospinning fluid level is kept in the same level. Key words electrospinning，electrical current，voltage ，humidity 0 引言 氯化钠；去离子水。 高压电源（Bertan 230-20R ）；Hewlett Packard HP974 万 静电纺丝又称电纺， 1934～1935 年，Formalas[1～7] 申请