壳聚糖海泡石吸附材料的制备论文.doc

PAGE 壳聚糖/海泡石吸附材料的制备 摘要 壳聚糖与海泡石都是天然的吸附性材料，本论文主要研究了壳聚糖与海泡石接枝工艺。以硝酸铈铵(CAN)为引发剂，将壳聚糖与用硅烷偶联剂改性后的海泡石接枝共聚，合成一种具有“壳聚糖—偶联剂—海泡石”的复合材料，通过实验优化了合成接枝物工艺条件：温度为80℃、反应时间为1.5h、壳聚糖与海泡石的单体比例为1：3、引发剂用量为壳聚糖的16％、偶联剂用量为海泡石质量的1.4% 用红外、差热法和扫描电镜对其结构和热性能进行了表征。同时设计两个吸附实验来探讨接枝产物的吸附性能，分别对亚甲基蓝的吸附和对Cu2+离子的吸附。吸附结果表明接枝产物有很高的吸附性能，对亚甲基蓝的平衡吸附量最大达4mg/g，去除率高达90%以上。对金属离子的最大吸附量可达17mg/g，去除率达到60%以上。 关键词：壳聚糖；海泡石；接枝共聚；吸附 Prepartion of chitosan and sepiolite complex adsorption material Name：LIU Wenjun Class：2005020403 Major：Materials Science and Engineering Supervisor：LIU Jing Abstract ：Both chitosan and sepiolite are crude absorb material. This article is mainly research the graft craftwork between chitosan macromolecule chain and sepiolite mineral. This experiment is use CAN as solicitation substance、chitoson and sepiolite which is after alter it character by use silicon alkyl mate-link-substance graft copolymerization ,compound a kind of complex material which is have the structure of chitosan-mate link substance-sepiolite.Optimizing a quite fine technics condition about the compound graft substance though the experiment：the graft efficienty is optimum when we ensure the optimum temperature 80℃、the reaction time 2h、monocase proportion is 1:3 in chitosan and sepiolite、solicitation substance dosage is 16% of chitosan、mate-link- substance dosage is account for sepiolites molar 1.4%. By infrared、heat defference method and scan electricity lens to analysis its structure and heat capability.Design two absorb experiment to discuss the absorb capability on graft product . Make the absorb experiment of tomethylene blueness and metal ion Cu2+ apart. The adsorb result indicate that graft product have a quite adsorb capability.The balance adsorb capacity most reach 4mg/g、wipe off rate is more than gouda 90% on tomethylene blueness .The most adsorb capacity can reach to 17mg/g、wipe off rate is more than 60% on metal ion. Key words：Chitosan； Sepiolite；Graft copolymerization；Adsorption 目 录