熔融钒渣直接氧化钠化提钒新工艺研究.pdfVIP

第33卷第6期 钢摇 铁摇 钒摇 钛 Vol郾33,No郾6 2012年12月 摇 摇 摇 摇 摇 摇 摇 摇 摇 摇 摇 IRON STEEL VANADIUM TITANIUM 摇 摇 摇 摇 摇 摇 摇 摇 摇 摇 摇 摇 December2012 苏收收收收收收苏收 收 钒钛提取苏 苏收收收收收收 熔融钒渣直接氧化钠化提钒新工艺研究 宋文臣,李摇 宏 (钢铁冶金新技术国家重点实验室,北京科技大学冶金与生态工程学院,北京100083) 摘摇 要:针对现行钒渣焙烧工艺中存在的钒渣高温物理热的浪费问题,提出“熔融钒渣直接氧化钠化提钒冶新工艺。 在现行工艺基础上,对新工艺进行了热力学和动力学的计算与分析,最后进行了新工艺的实验室模拟试验。 研究 结果表明:新工艺条件下,钒渣在反应过程中热量充足会保持良好的熔融状态;新工艺的动力学条件明显优越于现 行工艺;实验室试验结果验证了新工艺的可行性,在供氧充足,Na CO 用量为20% ~30%的条件下,钒渣氧化率约 2 3 为90%,钒浸出率在82%以上。 关键词:熔融钒渣;直接钠化;吹氧;浸出 中图分类号:TF841郾3,TF803.2摇 摇 文献标识码:A摇 摇 文章编号:1004-7638(2012)06-0001-05 A New Process for Vanadium Extraction from Molten Vanadium Slag by Direct Oxidation and Sodium Activating Method Song Wenchen,Li Hong (State Key Laboratory of Advanced Metallurgy,School of Metallurgical and Ecological Engineering,University of Science and Technology Beijing,Beijing 100083,China ) Abstract:To address the problem of heat waste of vanadium slag in the existing vanadium extraction process,anew processisproposedinthispaperto extractvanadiumfrommoltenvanadium slagby direct oxidation and sodium activating method. On the basis of current vanadium extraction process,the new processwas verified by thermodynamic and kinetic calculation and analysis,and then simulation tests were carried out inthelaboratory. Theresultsshow thatwith enough heat,vanadium slag can be kept in molten state during the vanadium extraction process. The dynamic conditions of the new process are no鄄 ticeably better thanthe existingprocess. The oxidizationrate of vanadium slag isabout90% andvanadi鄄 um leaching rate can reach 82% or above with enough oxygen and Na CO content at20%~30% of va鄄