LiODFB 电解液的高低温性能.docVIP

第 44 卷第 6 期 2013 年 6 月  中南大学学报(自然科学版) Journal of Central South University (Science and Technology)  Vol.44 No.6 June 2013  LiODFB 电解液的高低温性能 周宏明 1, 2 ，刘芙蓉 1 ，李荐 1, 2 ，方珍奇 1 ，李艳芬 1 (1. 中南大学材料科学与工程学院，湖南长沙，410083； 2. 湖南省正源储能材料与器件研究所，湖南长沙，410083) 摘要：采用 DSC、电化学工作站和电池测试系统研究 LiODFB/(EC+DMC+EMC)和 LiPF6/(EC+DMC+EMC)电解液 的热稳定性、高低温下的电化学窗口及其对铝箔集流体的稳定性、LiFePO4/G(石墨，graphite，简称 G)电池在 60 和?20 的高循环性能，通过 SEM 分析循环后的正负极极片形貌，探索高低温下电解液与极片的相互作用机理。 研究结果表明：LiODFB 电解液在 250 才会分解，而 LiPF6 电解液的分解温度为 120 ； ?20 和 60 时，LiODFB 电解液的电化学窗口及其对集流体铝箔的稳定性比 LiPF6 电解液的大；以 LiFePO4/G 为电极的 LiODFB 电池在?20 和 60 循环 100 次后的容量保持率均比 LiPF6 电池的大，LiODFB 电解液能够帮助石墨表面 SEI 膜的形成，而 LiPF6 电解液在高温下会产生 HF 破坏 SEI 膜，致使电池性能降低。 关键词：LiODFB；锂离子电池；高低温性能；热稳定性 中图分类号：TM911.3 文献标志码：A 文章编号：1672?7207(2013)06?2230?07  High and low temperature performance of LiODFB electrolyte ZHOU Hongming 1, 2 , LIU Furong 1 , LI Jian 1, 2 , FANG Zhenqi 1 , LI Yanfen 1 (1. School of Materials Science and Engineering, Central South University, Changsha 410083, China? 2. Hunan Zhengyuan Insititute for Energy Storage Materials and Devices, Changsha 410083, China) Abstract: The thermal stability of LiODFB/(EC+DMC+EMC) electrolyte and LiPF6/(EC+DMC+EMC) electrolyte, electrochemical window and stability with the aluminum foil at high and low temperature, and the cycle performance of LiFePO4/G (graphite) battery at 60 and ?20 ℃ were studied by DSC, electrochemical workstations and battery test system. SEM was used to analyse the anode morphology after cycle, and the interaction mechanism between the electrolyte and electrode at high and low temperature was also investigated. The results show that LIODFB electrolyte is decomposed at 250 ℃, while LiPF6 electrolyte has a decomposition temperature of 120 ℃. The electrochemical of LiODFB electrolyte and its stability with aluminum foil are superior to those of LiPF6 electrolyte at ?20 and 60 ℃. LiODFB battery w