湿热老化对热熔胶粘剂结构稳定性的影响.docVIP

2013 年 2 月　第 32 卷 第 2 期  实验研究  文章编号：1000-8241（2013）02-0181-04 湿热老化对热熔胶粘剂结构稳定性的影响  赵吉诗1  冯少广1  王舰2 李睿1  李荣光1 刘萌萌1 林伟3  杜中杰3 1. 中国石油管道科技研究中心 · 油气管道输送安全国家工程实验室，河北廊坊 065000； 2. 中国石油管道公司，河北廊坊 065000；3. 北京化工大学，北京 100029 摘要：热收缩带由辐射交联聚乙烯层、热熔胶粘剂及配套液态环氧底漆组成，其是 3PE管道应用最 广泛的补口材料。在热收缩带的补口过程中，主管道 PE层及焊缝两侧的环氧底漆层通过热熔胶粘 剂作用与热收缩带形成有效粘结，热熔胶粘剂的结构稳定性将对热收缩带补口的长期有效性产生重 要影响。为此，采用红外光谱（FT-IR）、凝胶渗透色谱（GPC）等分析方法研究了湿热老化对国内外 5种具有代表性的补口热收缩带热熔胶粘剂化学结构稳定性的影响，结果表明：湿热老化导致热熔 胶粘剂组分发生了明显的结构变化，一方面存在部分酯基水解和小分子脱除，另一方面部分组分存 在降解/交联反应。（表 2，图 3，参 8） 关键词：3PE；热收缩带补口；湿热老化；热熔胶粘剂；化学结构；稳定性 中图分类号：TE988　　　　　 文献标识码：A　　　　　 doi：10.6047/j.issn.1000-8241.2013.02.015 Influence of hygrothermal ageing on structural stability of hot-melt adhesives Zhao Jishi1, Feng Shaoguang1, Wang Jian2, Li Rui1, Li Rongguang1, Liu Mengmeng1, Lin Wei3, Du Zhongjie3 1. National Engineering Laboratory of Transportation Safety of Oil Gas Pipeline , PetroChina Pipeline R D Center, Langfang, Hebei, 065000; 2. PetroChina Pipeline Company, Langfang, Hebei, 065000; 3. Beijing University of Chemical Technology, Beijing, 100029 Abstract: The heat shrinkable sleeves composed of radiation cross-linked polyethylene layer, hot-melt adhesives and matching liquid epoxy primer is most widely used in the joint coating material in 3PE pipeline. During the joint coating process of heat shrinkable sleeves, PE layer of the main pipe and the epoxy primer on both sides of the weld seam form effective bonding with heat shrink sleeves through the action of hot-melt adhesives, and the structural stability of hot-melt adhesives will have a major impact on the long-term effectiveness of heat shrinkable sleeves joint coating. For this purpose, the impact of hygrothermal ageing on chemical structure stability of hot-melt adhesive is studied for 5 typical joint coating heat shrinkable sleeves at home and abroad with infrared spectroscopy (FT-IR) and gel permeation chromatography (GPC) method, etc. The results show that hygrothermal ageing cause significant structur