亚铜基离子液体催化氧化净化PH3.docVIP

第 44 卷第 3 期 2013 年 3 月  中南大学学报(自然科学版) Journal of Central South University (Science and Technology)  Vol.44 No.3 Mar. 2013  亚铜基离子液体催化氧化净化 PH3 瞿广飞，施玉琨，李江纳，宁平，张军，冯辉 (昆明理工大学环境科学与工程学院，云南昆明，650500) 摘要：以自主筛选的亚铜基离子液体为催化剂及反应介质，对含 PH3 的混合气进行液相催化氧化净化研究。采用 FT-IR 对单体[bmim]Cl 进行构象分析，测定亚铜基离子液体的热分解温度，考察混合气中温度、O2 浓度、[bmin]Cl 与 CuCl 摩尔比对磷化氢净化效率的影响，探讨离子液体催化氧化净化 PH3 的可能机理。研究结果表明：合成的 选择性好、稳定性高的亚铜基离子液体催化剂对 PH3 的净化效率长时间保持在 100%。较适宜的反应温度为 60 ； 随着混合气中 O2 含量的增加，吸收液对 PH3 的净化效率有所提高，在氧含量为 7.8%时净化效果最好；亚铜基离 子液体催化体系对 PH3 氧化有很好的催化作用，[bmim]Cl 与 CuCl 最佳摩尔比为 1:3。失活的催化剂经鼓氧再生后， 效率依然长时间保持在 97%，再生恢复性能较好。 关键词：磷化氢；过渡金属离子；离子液体；催化氧化 中图分类号：X701 文献标志码：A 文章编号：1672?7207(2013)03?1283?07  Catalytic oxidation of phosphine with Cu + -based ionic liquid QU Guangfei, SHI Yukun, LI Jiangna, NING Ping, ZHANG Jun, FENG Hui (Faculty of Environmental Science and Engineering, Kunming University of Science Technology, Kunming 650500, China) Abstract: Cu + -based ionic liquid was used as a self-screened catalyst and reaction medium of liquid phase catalytic oxidation to purify phosphine(PH3). FT-IR was chosen for the conformational analysis of the catalyst. The influences of temperature, oxygen content, and molar ratio of [bmim]Cl to CuCl on the purification efficiency of PH3 were explored. The possible mechanism of catalytic oxidation with Cu + -based ionic liquid was also proposed. The results illustrate that using the catalyst of target ionic liquid with excellent selectivity and high stability, the purification efficiency of PH3 can keep at 100% in Cu + -based ionic liquid catalytic system. The optimum reaction temperature is 60 ℃. As the O2 content increases, the catalyst plays a positive role on the catalytic oxidation process of PH3 and the optimum O2 content is 7.8%. The optimum molar ratio of [bmim]Cl to CuCl is 1:3. Regenerating the inactive catalyst solution, the purification efficiency of PH3 can still keep at 97% for a long time, indicating t