三种正畸用形状记忆合金丝的结构形貌分析.pdfVIP

《化学通报》在线预览版 三种正畸用形状记忆合金丝的结构形貌分析 聂琼 许天民 林久祥 (北京大学口腔医学院正畸科 北京 100081) 摘 要 本文对三种正畸用形状记忆合金镍钛丝(Tomy LH Titan，3M Ortho FormIII, Csds Ormco Damon Cuniti)的结构形 貌进行了对比分析。结果表明，Tomy LH Titan 镍钛丝具有和 3M Ortho FormIII, Csds Ormco Damon Cuniti 镍钛丝明显不 同的表面形貌结构，其表面呈现规整的微纳相间的沟槽结构。这种特有的沟槽结构使Tomy LH Titan 镍钛丝表现出不同 于其它两种镍钛丝的很强的疏水性能。此外，其横截面的微观结构也同样呈现其它镍钛丝所没有的、许多纵横交错的沟 壑结构。 关键词 形状记忆合金 镍钛丝 形貌 Morphology Structure Analysis of Three Orthodontic Shape Memory Alloy Wires Nie Qiong, Xu Tianmin, Lin Jiuxiang (Department of Orthodontics, School Hospital of Stomatology, Peking University, Beijing 100081) Abstract In this article the structure and morphology of three orthodontic nickel titanium shape memory alloy wires (3M Ortho FormIII, Tomy LH Titan and Csds Ormco Damon Cuniti, which are popularly used in today’s orthodontics) were investigated. The results showed that Tomy LH Titan wires had special micro-nano assisted plow groove-like structures, which led the surface of Tomy LH Titan wires exhibiting hydrophobic properties. While 3M Ortho FormIII and Csds Ormco Damon Cuniti without such micro-nano assisted plow groove-like structures, their surfaces appeared as hydrophilic. The cross section of Tomy LH Titan wires exhibited similar special characteristics as its surface morphologies compared with other candidates, which was probably close related with its excellent flexibility. Key Words Shape memory alloy wires, Nickel titanium wire, Morphology 某些合金的形状被改变之后，一旦加热到一定的跃变温度时，它又可以魔术般地变回到原来的形状， 人们把具有这种特殊记忆功能的合金称为形状记忆合金。镍-钛合金的形状记忆功能起源于 Ni －Ti 组成 的二元合金内其晶体结构的排列方式在温度或外力的作用下发生了澳氏体↔马氏体的可逆转变。每种以 一定元素按一定重量比组成的形状记忆合金都有一个转变温度。在这一温度以上将该合金加工成一定的 形状，然后将其冷却到转变温度以下，通过外力就可以任意改变其形状，只要再加热到转变温度以上， 该合金便会自动地恢复到原先在转变温度以上加工成的形状。