污泥龄对膜生物反应器中溶解性荧光物质特性的影响.pdf

净水技术2012 ，31 （2）：52-57 Water Purification Technology Vol. 31, No. 2, 2012 污泥龄对膜生物反应器中溶解性荧光物质特性的影响 1 2 蔡伟娜 ，何 磊 （1.上海市水务规划设计研究院，上海 200232 ；2. 同济大学环境科学与工程学院，上海 200092） 摘 要 采用三维荧光（EEM）光谱技术分析了膜-生物反应器（MBR）处理餐饮废水过程中的各种溶解性有机物（DOM），并对 比研究不同污泥龄（SRT）条件下DOM 的EEM 光谱的迁移变化特性。结果表明各种DOM 的荧光物质中，普遍存在以色氨酸为 代表的蛋白质类物质，且溶解性膜污染中只有高、低激发波长色氨酸，表明蛋白质类物质是导致膜污染的重要因素。腐殖酸溯 源又表明进水及出水DOM 中的腐殖酸以微生物代谢产生的带有荧光基团的腐殖酸类为主。 关键字 污泥龄(SRT) 膜生物反应器(MBR) 溶解性荧光物质 三维荧光光谱 中图分类号：TU992 文献标识码：A 文章编号：1009-0177 （2012）02-0052-06 Influence of Sludge Retention Time (SRT) on Characteristics of Dissolved Fluorescence Matters in Membrane Bioreactor (MBR) 1 2 Cai Weina , He Lei (1.Shanghai Water Planning and Design Research Institute, Shanghai 200232, China; 2.College of Environmental Science and Technology, Tongji University, Shanghai 200092, China) Abstract Through excitation-emission matrix (EEM) fluorescence spectra analysis, the characteristics of dissolved organic matter (DOM) in the process of membrane bioreactor used for restaurant wastewater treatment were studied. The influence of sludge retention time (SRT) on fluorescence migration features of DOM was analyzed. Results show that protein substances (e.g., tryptophan) exist in all the DOM. Only high- and low-excitation wavelength tryptophan is found in dissolved membrane foulants, which implies protein substances play a key role in membrane foulants. Humic acid produced by microbial metabolism with fluorescence-based groups is primary source of humic acid in DOM. Keywords sludge retention time (SRT) membrane bioreactor (MBR) dissolved fluorescence matter matrix fluorescence spectrum [1-2] 膜-生物反应器（