三取代苯基咪唑衍生物的制备及其双光子吸收性能研究.pdfVIP

化学通报 2005 年 第 68 卷 w116 三取代苯基咪唑衍生物的制备及其双光子吸收性能研究 * 刘旭峰 钟增培 许遵乐 ( 中山大学化学与化学工程学院 广州 510275) 摘 要 用 4-取代二苯乙二酮和对苯二甲醛在乙酸和乙酸铵的存在下加热反应，合成了系列 2-(4- 甲酰苯基)-4,5-二(4-取代苯基)咪唑衍生物，用核磁共振、质谱和元素分析方法进行了表征。测定 了它们的线性吸收光谱、单光子荧光光谱、荧光量子产率和双光子吸收截面，发现这类 2,4,5-三苯基 咪唑类化合物均具有较好的双光子诱导蓝光发射性能。双光子诱导荧光法测定结果显示，这类蓝光发 射的咪唑类化合物中，最大的双光子吸收截面高达 123.8GM，最高的荧光量子产率达 96.1% 。 关键词 双光子吸收 双光子诱导荧光 量子产率 双光子吸收截面 Preparation and Characterization of Two-photon Absorption Materials of 4-[4,5-Bis-(4-substituted-phenyl)-1H-imidazol-2-yl]-benzaldehyde * Liu Xufeng, Zhong Zengpei , Xu Zunle (School of Chemistry and Chemical Engineering, Sun Yet-Sen University, Guangzhou 510275) Abstract A series of 2,4,5-triarylimidazoles have been synthesized and characterized. All the four compounds have been identified by way of 1H NMR, MS and elemental analysis. Their linear absorption spectra and single-photon induced fluorescent spectra were measured, too. They were all found to have large two-photon cross-section and very high quantum yields. Especially, the quantum yield of the compound 4-[4,5-Bis-(4- substituted-phenyl)-1H-imidazol-2-yl]-benzaldehyde (compound B) is as high as 96.1%, the two-photon absorption cross-section of compound C is 123.8GM. The quantum yield and two-photon absorption cross-section change obviously by the modifications of end groups. Key words Two-photon absorption, Two-photon induced fluorescence, Quantum yield, Two-photon absorption cross-section 双光子吸收是指物质分子在强光作用下同时吸收两个光子通过一个虚拟中间态而达到激发 态的