淀粉接枝阳离子聚丙烯酰胺水分散体系的研究.pdfVIP

淀粉接枝阳离子聚丙烯酰胺水分散体系的研究 摘 要 本文在综合相关文献基础上,对淀粉接枝阳离子聚丙烯酰胺S-g-CPAM水 分散体系的制备规律进行了研究;同时初步探讨了淀粉接枝阳离子聚丙烯酰胺 水分散体的絮凝性能。 1、以丙烯酰胺AM单体为主要原料,引入甲基丙烯酰氧乙基三甲基氯化 铵DMC为阳离子共聚单体,以聚甲基丙烯酰氧乙基三甲基氯化铵PDMC为分 散剂,选择过硫酸铵/亚硫酸氢钠氧化还原体系为引发剂,在硫酸铵溶液中采用 水分散聚合技术制备了稳定的 S-g-CPAM 共聚物。 2、系统考察了淀粉与单体质量比、阳离子单体含量、引发剂用量、分散剂 分子量和用量、无机盐浓度、反应温度和时间等因素对水分散聚合反应、产品 特性接枝率、接枝效率和体系稳定性的影响。通过单因素实验确定昀佳反应 条件为:淀粉与乙烯基单体质量比为 1:3,阳离子单体含量为 10.0%,引发剂用 -3 -1 4 量为 2.45×10 mol?L ,分散剂分子量为 43.4×10 ,用量为 2.0%,无机盐浓度 为 35%-40%,反应温度为 60℃,反应时间为 3h。 3、利用红外光谱FTIR等分析手段对产品进行了表征,验证了淀粉与 AM、 DMC成功进行了接枝共聚反应。 4、通过高岭土模拟废水絮凝实验,考察了水分散型 S-g-CPAM 的阳离子度、 接枝率和投加量对絮凝性能的影响。结果表明:在阳离子度为 10.0%时,接枝 -1 率越高,絮凝性能越好,其昀佳用量为 2.0mg?L 。 关键词:阳离子聚丙烯酰胺 水分散聚合 淀粉 接枝 絮凝 STUDY ON AQUEOUS DISPERSIONPOLYMERIZATION OF STARCH GRAFT CATIONIC POLYACRYLAMIDE ABSTRACTOn the basis of the relevant literature,the synthesis of aqueous dispersion polymerization of starch graft cationic polyacrylamideS-g-CPAM was studied in this paper. At the same time, the flocculation performances of the prepared dispersions were discussed1. AcrylamideAM was selected as main raw material, dimethylaminoethyl methacrylate methyl chlorideDMC as the cationic co-monomer, polydimethylami- noethyl methacrylate methyl chloridePDMC as stabilizer and redox system of ammonium persulfate/sodium bisulfite as initiator, the S-g-CPAM copolymer was synthesized by aqueous dispersion polymerization in ammonium sulfate solution2. The effects of varying factors, i.e. the weight ratio of starch with monomers, the DMC content, the dosage of initiator, the concentration and molecular weight of the dispersant, the concentration of AS, the reaction temperature and time on the polymerization process, the product charactersgrafting and grafting efficiency and the stability of the system were investigated. Using the single-factor experiments, the optimum conditions of synthesis were determined as follows: the weight ratio of starch with monomers was 1:3, the content of cationic monomer was 10.0%, the -3 -1 dosage of ini