Pt_TiO2纳米管阵列制备及其气敏性能研究.docVIP

  Pt/TiO2 纳米管阵列制备及其气敏性能 研究# 袁宝1，王岩1，卞海东1，张剑芳1，沈天阔1，惠佳宁1，舒霞1,2，吴玉程1,2** 5 10 15 20 25 30 35 40 （1. 合肥工业大学材料科学与工程学院，合肥 230009； 2. 功能纳米材料与器件安徽省重点实验室，合肥 230009） 摘要：采用阳极氧化法制备了高度有序密致排列的 TiO2 纳米管阵列，制得的 TiO2 纳米管阵 列在氯铂酸与柠檬酸的混合溶液中经溶剂热还原法得到了 Pt 纳米颗粒修饰的 TiO2 纳米管阵 列(Pt/TiO2)。利用 SEM、XRD、XPS、FETEM、EDS 分析了 Pt 修饰 TiO2 纳米管阵列的表 面形貌和微观结构。结果表明，TiO2 纳米管阵列管径约 120nm，管长 13μm，Pt 纳米颗粒均 匀分布在纳米管的管口及管内壁，直径约 20nm。以 Pt/TiO2 纳米管阵列作为旁热式气敏元器 件材料，研究了一定工作温度条件下，Pt/TiO2 对酒精气体及氧气的气敏响应。Pt 颗粒修饰 的 TiO2 纳米管阵列气敏性能相对于纯 TiO2 纳米管阵列有显著提高，且十次循环测试后对酒 精仍具有良好的气敏响应特征。通过气敏元器件对还原性气体和氧化性气体的响应曲线分 析，讨论了 TiO2(Pt/TiO2)纳米管阵列的气敏传感机理。 关键词：阳极氧化；TiO2 纳米管阵列；Pt 纳米颗粒；气敏性能；酒精气体 中图分类号：TB34 Pt nanoparticles decorated TiO2 nanotube arrays: preparation and application for high sensitive gas sensing Yuan Bao1, Wang Yan1, Bian Haidong1, Zhang Jianfang1, Shen Tiankuo1, Hui Jianing1, Shu Xia1,2, Wu Yucheng1,2 (1. School of Materials Science and Engineering, Hefei University of Technology, HeFei 230009; 2. Key Laboratory of Functional Nanomaterials and Devices of Anhui Province, HeFei 230009) Abstract: Highly ordered TiO2 nanotube arrays were prepared by anodic oxidation, and Pt nanoparticles were deposited on TiO2 nanotube arrays by solvothermal reduction method in the solution containing chloroplatinic acid and citric acid. Pt nanoparticles modified TiO2 nanotube arrays were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), field emission transmission electron microscopy (FETEM) and energy dispersive spectroscopy (EDS). The results showed that the TiO2 nanotubes array with 120 nm in diameter and approximate 13 μm in length, and the deposited Pt nanoparticles with a particle size about 20nm were in an ordered assembly on the nanotubes with a uniform distribution. The as-prepared TiO2 nanotube arrays and Pt/TiO2 nanotube arrays were both evaluated for ethanol and oxygen gas sensing. The results showed that the Pt/TiO2 nanotube arrays exhibited much higher sensitivity, as