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Crystal structure, thermogravimetric analysis and
electrochemical properties of the cobalt(Ⅱ) complex of
1-(4-methoxybenzyl)-2-(4-
5
10
15
20
25
30
methoxyphenyl)benzimidazole
#
YANG Hongwei, YUE Fan, WANG Jide**
(Key Laboratory of Oil and Gas Fine Chemicals, Ministry of Education and Xinjiang Uyghur
Autonomous Region, College of Chemistry and Chemical Engineering, Xinjiang University,
Urumqi, 830046)
Abstract: Cobalt (II) complex of 1-(4-methoxybenzyl)-2-(4-methoxyphenyl)benzimidazole have been
synthesized and characterized by IR, X-ray diffraction, thermogravimetric analysis, and cyclic
voltammetry. This complex crystallized in the monoclinic space group P2/n with the cobalt atom
adopting a four-coordinate distorted-tetrahedral environment, crystal of the complex: a=12.88 (?),
b=9.83( ?),c=15.44( ?), α=γ=90°, V=1953.0(5) ? 3. The cobalt adopts a four-coordinate
distorted-tetrahedral environment by two nitrogen atoms and two terminal chlorine atoms. The
electrochemical characteristics have been studied by cyclic voltammetry, and the result proved that the
coordination of the ligand with cobalt(II) increased the electrochemical activity of the ligand. The
complex was characterized by thermogravimetric analysis revealed it has good thermal stability..
Key words: Benzimidazole derivative; Schiff base; crystal structure; Co(II) Complex
0 Introduction
Benzimidazoles are of considerable chemical and biological interest as their derivatives have
found wide use as anthelmintic agents in both human and veterinary medicine. The coordination
chemistry of azoles acting as ligands in transition metal compounds has led to the extensive study
of chelating ligands incorporating benzimidazole groups for modeling biological systems [1-3].
We have reported that the reaction of p-methoxybenzaldehyde with o-phenylenediamine yielded
the benzimidazole derivative (1-(4-methoxybenzyl)-2 -(4-methoxyphenyl)benzimidazole) 1 [4]. In
order to examine the characteristics of the correspond
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