生物质燃烧烟尘中糖类和甾醇的分析概述.docVIP

江苏沿江城市PM10和PM2.5中水溶性离子研究 [1]、陈辰[2][1] 、张甦[1] [1] 江苏省环境监测中心，南京，210036 [2]南京信息工程大学环境科学与工程学院南京 210044 摘要： 2012年3月和6月在江苏沿江七市（镇江、常州、无锡苏州、扬州、泰州和南通）采集大气PM10PM2.5样品，运用离子色谱法，分析无机水溶性离子成分，并对其组成、相关性、结合形式和来源解析等方面进行研究。结果表明，春季苏南四市PM10和PM2.5质量浓度低于苏中三市，夏季反之； PM10和PM2.5具有较好的相关性，水溶性离子在PM2.5中所占的比例一般高于PM10中的比例，SO42-、NO3-、NH4+是颗粒物中水溶性离子的主要成分，占总量的80%左右。PM10和PM2.5中的SO42-和NO3-、NH4+和SO42-、NO3-之间均具有较好的相关性；PM10中Ca2+和Mg2+显著相关，细粒子中相关性较小。NH4+和SO42-、NO3-主要以( NH4) 2SO4和NH4NO3存在于可吸入颗粒物中。春夏两季，江苏沿江城市PM10和PM2.5中的SOR均大于NOR，SO2在大气中的转化率比NOX的转化率要高；苏南地区PM10和PM2.5中的SOR和NOR比苏中要高。运用[SO42-]/[NO3-]的比值法，研究颗粒物污染来源，表明春季的污染源主要为流动源，夏季为固定源。运用因子分析分析颗粒物来源，燃煤、交通运输、生物质燃烧、土壤和建筑地表扬尘是春夏两季江苏沿江城市可吸入颗粒的主要污染源 关键词：PM10PM2.5，水溶性离子， of water-soluble ions in PM10 and PM2.5 along the Yangtze River in Jiangsu City Chencheng[1] ,Chenchen[2] ,TANG Li-li[1] ,ZHANG Su[1] （1．Jiangsu Environmental Monitoring Cen~e，Nanjing210036，China； 2．School of Environmental Science and Engineering，Nanjing Information Engineering University，Nanjing 210044，China） ABSTRACT After collected atmospheric PM10 and PM2.5 samples in Jiangsu seven cities(Zhenjiang, Changzhou, Wuxi, Suzhou, Yangzhou, Taizhou and Nantong) along the Yangtze River in 2012 March and June, analyzed the soluble ions of various water one by ion chromatography, and researched its composition, correlation and the existence of form, source analysis etc. The results show that, the concentration of PM10 and PM2.5 in the four cities of South of Jiangsu(SJ) is lower than the three cities in the central of Jiangsu(CJ) in the spring , summer and vice versa ; PM10 and PM2.5 have good correlation, water-soluble ions as a percentage of PM2.5 is generally higher than the proportion of PM10, SO42-, NO3-, NH4+ is the main component of particulate water-soluble ions, accounting for about 80% of the total. The ratio of [SO42-]/[NO3-] showed that the main pollution source of spring is flow, summer is fixed sources. SO42- and NO3-, NH4+ and SO42-, NO3- have good correlation in the PM10 and PM2.5 ; Ca2+ and