New BaBrCl: Eu^2+ phosphors for X-ray image recording.pdfVIP

New BaBrCl: Eu^2+ phosphors for X-ray image recording.pdf

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Chinese Science eulletin @ 2009 SCIENCEfNCHINAPRESS 一 Springer New BaBrCI:Eu phosphorsforX-rayimagerecording WANG YongSheng,MENG XianGuo&HEDaWei KeyLaboratoryofLuminescenceandOpticalInformation,InstituteofOptoelectronicTechnology,BeijingJiaotongUniversity,Beijing 100044.China PhotostimulatedIuminescencefPSL)isobservedjnBaBrChEu afterX—rayjrradiationatroom tem. perature.ItissuggestedbyPSLstimulationspectrumanddifferenceabsorptionspectrum (DAS)thatF centers areformed upon X—ray irradiation and both spectra show two bandswhicharecentered at about550nm and 675 nm respectively.ThisenablestheuseofsemiconductorIight-emitting diodes (LED)insteadofgaslasersforphotostimulation.ThePSLintensityincreaseslinearlywithX-rayirra. diationdoseincreasing.andtheconversionefficiencyis29% thatforthestandardcommerciaIstorage phosphorBaFBr-Eufrom Fuiiimagingplate. PSL,colorcenter,electrontrapping There are now severaldigitaltechnologieswhich are nm).frequencydoubledYAG:Nd” laser(532nm)and competitors of the traditionalphosphor/photographic He.Nelaserr633nm)accordingtoitsPSLstimulation film method for recording images in industrialand spectrum.By increasingtheratioofF toBrordoping medicalX—ray radiography.Thebestestablishmentof with otherionssuch asCaz. Sr andAr).thePSL theseisthecomputedradiographyusingX—ray storage stimulationDeak canberedshifted to 600nm oreven phosphorsfXRSPs)asscreens1.A largenumberof 645 nm[12,131 . ThePSL found in s0me g1assceramics storage phosphors have been studied, including comesusuallyrfom BaC】2:Eu andBaBr2:Eu crystal一 BaFX:Eu“ (X:ClBr,I)I , , alkalihalidesdopedwith 1ites.whichmeanstherequired stimulation energy is Eu2+forGa+)f6,7。BaLiF3:Eu2+8『,91 , , a

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