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20 2 2010 2
Vol.2 No.2 The Chinese Journal of Nonferrous Metals Feb. 2010
1004-0609(2010)02-0354-09
( 410083)
QM-1SP
(SEM)−X
80.5%
6 h15 min 3 h −(Mechano-chemical)
−
TF813 A
Effects of mechanical activation on alkaline leaching and
physicochemical properties of hemimorphite
CAO Qin-yuan, LI Jie, CHEN Qi-yuan
(School of Chemistry and Chemical Engineering, Central South University, Changsha, 410083)
Abstract: In order to accelerate the leaching rate of zinc in alkaline solutions, QM-1SP type planetary ball mill was used
to enhance the leaching of hemimorphite from Lanping, Yunan Province in NH -NH Cl solutions. The influence of
3 4
mechanical activation on the crystal structure and leaching behavior of hemimorphite was investigated by SEM, particle
distribution analysis, TG-DSC analysis and XRD analysis. The results indicate that, by mechanical activation the size of
the ore particles decrease, the surface crystal layer of the ore transfers to amorphous, the lattice distortion increases
obviously and the hemimorphite is in an activated metastable state. The accumulation of the insoluble products on the ore
is blocked, the stagnation period in non-milled leaching process is eliminated and the leaching rate of zinc increases
rapidly. In non-milled leaching process, it needs 6h to get extraction ratio of 80.5%, while in the milled-leachi
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