纳米颗粒的表面改性及其对ZrB2-SiCnp复合材料的影响.pdfVIP

中国科技论文在线 纳米颗粒的表面改性及其对ZrB2-SiCnp复 # 合材料的影响 韩文波，刘强** （哈尔滨工业大学复合材料与结构研究所，哈尔滨 150001 ） 摘要：采用氢氟酸对原始纳米SiC 颗粒进行表面改性，以制备稳定分散的纳米SiC 浆料。借 助XRD 、比表面仪和扫描电子显微镜等对改性前后纳米SiC 颗粒进行了表征，发现SiC 颗 粒表面的表面的SiO2 杂质被去除了，颗粒之间无明显团聚现象。根据比表面积结果，确定 最佳的改性时间为15min。通过比较改性前后两种复合材料的微观组织和力学性能，结果表 明，纳米SiC 颗粒的表面改性可以显著改善第二相颗粒在基体中的分散均匀性，有效抑制基 体晶粒的长大，从而使材料的力学性能显著提高，其最高弯曲强度和断裂韧性分别达到 1009.1MPa 和6.8MPa·m1/2 ，比改性前材料的相应数值分别提高了44%和10%。 关键词： 表面改性；纳米颗粒；氢氟酸；微观组织；力学性能；复合材料 Surface modification of nano-sized SiC particles and its effects on ZrB2-SiCnp composite Han Wenbo, Liu Qiang (Center for Composite Materials, Harbin Institute of Technology, Harbin 150001) Abstract: In this paper, raw nano-sized SiC particles were modified by HF to obtain SiC stable dispersed suspension. By means of XRD, BET and SEM, nano-sized SiC particles before and after surface modification were characterized. It was revealed that the surface modification can clean off SiO2 adhering to the surface of SiC particles and help to promote the particle dispersibility. A result of BET indicate the optimal treatment time of 15 min. By comparison with the mechanical properties and microstructure of ZrB2-SiCnp composite with raw nano-sized SiC particles, it was found that an uniform dispersion of modified nano-sized particles disperse throughout ZrB2 matrix, impeding the growth of ZrB2 grain and improving the mechanical properties of composite, consequently. The highest flexural strength and fracture t