增塑聚乳酸性能的研究3.pdfVIP

　　塑 　料 2009 年 　38卷 　第 2 期 赵梓年等 ———增塑聚乳酸性能的研究 增塑聚乳酸性能的研究 赵梓年 ,王 　红 (天津科技大学材料科学与化学工程学院 ,天津 　300457) 　　摘要 :采用熔融共混的方法制备增塑聚乳酸 ,研究不同增塑剂对聚乳酸力学性能、流变性能、结晶性能以及降解性 能的影响 。结果表明:增塑剂品种不同对聚乳酸的增塑效果不同 ,其中三醋酸甘油酯的增塑效果最好 ;增塑聚乳酸的 表观黏度随着剪切速率的增大而下降 ,改善了聚乳酸的加工性能 ;增塑聚乳酸的结晶速率加快 ,片晶厚度减小 ;增塑聚 乳酸的降解速率加快 。 关键词 :聚乳酸 ;增塑剂 ;共混 ;结晶; 降解 中图分类号 : TQ32 1　文献标识码 : A 　文章编号 : 1001 - 9456 (2009) 02 - 0088 - 04 Properties of P la stic ized PLA ZHAO Zin ian,WAN G Hong ( Tianj in U n iversity of Science Technology, Co llege M aterial Science Chem ical Engineering, Tianj in 300457, Ch ina) 　　A b stract: The p la sticized PLA was p rep ared by m ean s of m elting b lend. The effects of differen t p lasticizers on the m echan ical p rop erties, rheological p rop erties, crystal p rop ertie s and degradab le p rop ertie s of PLA were studied. The re su lts showed that different p la sticizers had different p la sticizing effects on PLA , among wh ich the effect of TA c wa s the best. The app arent visco sity of p la sticized PLA was declined w ith shear rate increa sing, the p rocessing p rop erties of PLA were imp roved. Crystallization rate of p la sticized PLA wa s increa sed and lam ellar th ickne ss wa s decrea sed. The degradation rate of p la sticized PLA was accelerated. Key word s: PLA ; p la sticizers; b lending; crystallization; degradation ( ) 　　近年来 , 由于废弃塑料引发越来越严重的环境污染问题 ,使