电化学法水处理新技术——杀菌灭藻.pdfVIP

第 20 卷增刊 环 　境 　科 　学 　学 　报 Vol. 20 ,Suppl 2000 年 9 月 ACTA SCIEN TIAE CIRCUMSTAN TIAE Sep. ,2000 ( ) 文章编号 2000 增刊007505 　　　中图分类号:X52 　　　文献标识码 :A 电化学法水处理新技术 ———杀菌灭藻 ( 同济大学城市污染控制国家工程研究中心,上海　200092) 吴星五 ,高廷耀 ,李国建　 摘要 :用电化学方法杀菌灭藻的水处理技术. 结果表明 : 电解产生的活性物质对杀菌起到关键的作用; 以钛为基体外涂含铱 ( ) 等贵金属氧化物的阳极可催化产生活性氧 H O 、O 、O 等 等杀菌性活性物质 ;增加电流密度、停留时间和极水比可以提高 2 2 3 杀菌效果 ;通过监测处理后水样中溶解氧的变化 ,确认处理器具有灭藻的功能 ;处理器的性能 ,达到水流 10 s 单程通过 ,一般 ( ) 3 细菌的杀灭率 99. 99 % ,耗电量 0. 1 kW ·h / m . 关键词 :水处理 ; 电化学;杀菌灭藻 Ne w electrochemical technique of water treatment ———disinfection and algae killing (National Engineering Research Center for Urban Pollution Control , Tongji WU Xingwu , GAO Tingyao ,L I Guojian 　 University , Shanghai 　200092) Abstract :A new electrochemical technique for water treatment , disinfection and algae killing was studied. The results indicated that : The active species electrochemically produced at the anode played the most important role for the disinfection process. The metal ( Ir and so on ) oxides coated titanium electrode catalytically generated active oxygen species ( such as H O 、·OH 、O 、O ) which were 2 2 3 strong bactericidal agents. The disinfection efficiency could be increased by increasing the current density ,retention time and the rate of anode effective area to the inner water volume. By monitoring the dissolved oxygen ,it is confirmed that the electrochemical water treat