二氧化钛双粒径组合对染料敏化电池光电性能的影响研究.pdfVIP

中国科技论文在线 二氧化钛双粒径组合对染料敏化电池光电 性能的影响研究# 王春阳，李祥，周一浩，林高庭，牛继南** 5 （中国矿业大学材料科学与工程学院,江苏徐州 221116 ） 摘要：本文以不同粒径的纳米 TiO2 粉体为原料，制备了单粒径 TiO2 薄膜以及双粒径TiO2 组合薄膜，并测试了它们的光电转换性能。结果表明，以单粒径30nm TiO2 制备的薄膜光电 转换效率最高，为6.28% ；随着单粒径尺寸的增大或减小，TiO2 薄膜的转换效率都降低；以 10 粒径分别为45nm 和60nm 的TiO2 等质量混合制备的薄膜在所有双粒径复合薄膜中光电转换 效率最高，为4.62% 。不同粒径组合膜层的性能差别可能是因为有效比表面积的不同所引起， 而粒径组合引起的晶粒间隙大小和晶体自然比表面积间的协调又决定了样品间的有效比表 面积。 关键词：染料敏化电池；二氧化钛；阳极；粒径组合 15 中图分类号：TK514 Effect of combination of dual particle sizes titanium dioxide on photoelectric performance of DSSC WAN Chunyang, LI Xiang, ZHOU Yihao, LIN Gaoting, NIU Jinan 20 (School of Materials Science and Engineering, China University of Mining and Technology, Xuzhou, Jiangsu 221116) Abstract: In this paper, with different sizes of nano TiO2 powder as raw material, the films with the single particle size of TiO2 and with the dual particle sizes of TiO2 were prepared and their photoelectric conversion efficiency were measured. The results showed that the film with a single 25 particle of 30nm produced the highest photoelectric conversion efficiency, 6.28%; and with the increase or the decrease of particle size, the efficiency of TiO2 films reduced; the film composed of 45nm and 60nm TiO2 by equal quality had the highest photoelectric conversion efficiency in all dual particle sizes films, which was 4.62%. The major factor to affect the efficiency of dual particle combination anode was the effective surface area, which was controlled by the coordination between 30 the grain gaps which was different in each combi