聚（3-羟基丁酸酯-co-3-羟基戊酸酯）热塑性聚氨酯复合材料的制备及性能研究.pdfVIP

中国科技论文在线 聚 （3-羟基丁酸酯-co-3-羟基戊酸酯）/热塑 # 性聚氨酯复合材料的制备及性能研究 王世超，龚雪，彭程，相恒学，周哲，单桂芳，朱美芳** 5 （纤维材料改性国家重点实验室，东华大学材料科学与工程学院，上海，201620 ） 摘要：本文针对聚 （3-羟基丁酸酯-co-3-羟基戊酸酯）（PHBV）脆性大的缺点，选用环境友 好型热塑性聚氨酯 （TPU）作为增韧剂，采用熔融共混的方法制备了生物相容性好、力学性 能佳的 PHBV 基复合材料，并对其表面形貌、晶体结构、热学性能以及力学性能进行了表征。 SEM 和 DMA 结果显示，PHBV 与 TPU 两相之间出现明显的界面分离，为不相容体系；POM、XRD 10 及 DSC 结果表明，TPU 的加入抑制了 PHBV 球晶的径向生长速率，但并未破坏其晶体结构。 此外，TPU 的加入有效地提高了复合材料的韧性。相比纯 PHBV，P/30T （30wt%TPU）复合材 料的断裂伸长率提高了 200%左右。 关键词：高分子材料；聚 （3-羟基丁酸酯-co-3-羟基戊酸酯）；热塑性聚氨酯；增韧改性 中图分类号：TQ320.1 15 Preparation and Characterization of PHBV/TPU Composites WANG Shichao, GONG Xue, PENG Cheng, XIANG Hengxue, ZHOU Zhe, SHAN Guifang, ZHU Meifang 20 (State Key Laboratory for Modification of Chemical Fibers and Polymer Materials,College of Materials Science and Engineering, Donghua University, Shanghai 201620) Abstract: PHBV/TPU composites were prepared in order to obtain the environmental friendly composites based on PHBV with good biocompatibility and mechanical properties. Surface morphology, crystal structure, thermal properties and mechanical properties of composites were studied. 25 The results of SEM and DMA showed that PHBV was immiscible with TPU. In addition, the addition of TPU inhibited the radial growth rate of PHBV, however, the crystal structure of PHBV did not change, which was demonstrated by the results of POM，XRD and DSC.