利用十二胺盐酸盐从钾混盐中直接浮选钾盐镁矾的研究.pdfVIP

中国科技论文在线 利用十二胺盐酸盐从钾混盐中直接浮选钾 盐镁矾的研究# 王楠，程芳琴** 5 （山西大学资源与环境工程研究所，国家环境保护煤炭废弃物资源化高效利用技术重点实验 室，太原 030006） 摘要：盐湖卤水在浓缩结晶时容易生成同时含有光卤石和钾盐镁矾的钾混盐，此类固相盐的 分离难度较大。本文利用十二胺盐酸盐直接从钾混盐中浮选钾盐镁矾，实验发现钾盐镁矾的 10 收率最高可以达到65.28% 。确定的优化操作工艺参数为捕收剂浓度1×10-3mol/L 、pH 值9.5 、 浮选温度20℃，在此条件下浮出物中钾盐镁矾的含量达到了85.65%，而浮选尾矿中80.21% 是光卤石，证实十二胺盐酸盐可以对钾混盐中的两种组分起到有效的分离作用。 关键词：浮选；十二胺盐酸盐；钾盐镁矾；光卤石 中图分类号：TQ028.9 文献标识码：A 15 Investigation of Flotation of Kainite from Potassium Mixed Salt using Dodecyl Amine-Hydrochloride as Collector WANG Nan, CHENG Fangqin (State Environmental Protection Key Laboratory on Efficient Resources-utilization Techniques of 20 Coal Waste, Institute of Resources and Environment Engineering, Shanxi University, Taiyuan 030006) Abstract : Salt lake brine can easily formate potassium mixed salt containing both carnallite and kainite during the crystallization process. This kind of solid salt is hard to separate. This paper used dodecyl amine-hydrochloride to flotate kainite directly from potassium mixed salt. The results 25 showed that the recovery of kainite reached as far as 65.28%. Kainite takes up 85.65% of the floated property whereas Carnallite occupied 80.21% of the tailings when DAH was 1×10 -3mol/L in concentration with the pH value of 9.5 and the temperature of 20 ℃. This confirms that dodecyl amine-hydrochloride can efficiently separate the two components in potassium mixed salt. Key words: Froth flotation ；Dodecyl amine-hydrochloride ；Kainite ；Carnallite 30 0 引言 含钾盐湖卤水的盐田作业主要以卤水为原料，利用太阳能和风能日晒蒸发、浓缩、结 晶，分离卤水中的一般盐类，其主要产品之一是晒制的光卤石原矿。然而，在生