纳米胶囊潜热型热流体的制备及传热性能.pdfVIP

中国科技论文在线 纳米胶囊潜热型热流体的制备及传热性能 凌子夜，王磊，方玉堂，高学农，张正国 (华南理工大学传热强化与过程节能教育部重点实验室，广州510640) 摘要：采用超声乳化、原位细乳液聚合的方法制备出了壳体为聚苯乙烯，芯材为RT26 的纳 米胶囊相变粒子。纳米胶囊的平均粒径约为130 nm，固-液及液-固相转变温度和相变潜热分 别为26.28 ℃、72.59 J/g 和23.12 ℃、73.6 J/g, ，相变温度与RT26 基本相当。在完全湍流条 件下，研究了纳米胶囊相变粒子质量分数为6%条件下潜热型热流体的传热性能，结果表明， 在相同压降下潜热型热流体的传热系数比水提高了50%左右。 关键词：纳米胶囊；相变材料；热流体；传热 中图分类号：TQ025 文献标志码：A Preparation and heat transfer performance of latent typed thermal fluid with nanoencapsulated phase change material Ling Ziye, Wang Lei, Fang Yutang, Gao Xuenong, Zhang Zhengguo (The Key Laboratory of Enhanced Heat Transfer Energy Conservation, Ministry of Education, South China University of Technology, Guangzhou 510640, China) Abstract: Nano-encapsulated phase change materials with polystyrene as shell and RT 26 as core have been synthesized by ultrasonic technique and mini-emulsion in-situ polymerization. The average particle size of the prepared nano-capsules was 130 nm. The phase change temperature was 26.68 ℃ and latent heat 72.59 J/g for the solid-liquid phase change, while they were 23.06 ℃ and 73.16 J/g, respectively, for the liquid-solid phase change. The phase change temperature correspondent to that of RT 26. Under full turbulence conditions, the heat transfer performance of thermal fluid with 6% mass fraction of the nano-capsule was tested. The result showed that heat transfer coefficient of the thermal fluid was l.5 times as large as that of water at the same pressure drop. Key words: nanocapsule; phase change material; thermal fluid; heat transfer 在航空航天技术、微电子、激光加工和燃料电池等领域，通常涉及到微通道的传热问题。 受加工技术和加工成本的限制，在微通道内加工翅片结构或粗糙元进行传热强化十分困难。 因此，必须发展新的强化传热技术。 潜热型热流体是近些年发展起来的一种强化传热新技术，它是指将相变粒子添加到传热 流体中，在传热过程中，相变材料在壳体内发生固-液或固-固相变，释放（吸收）相变潜热， 利用相变材料大的潜热质来提高流体的比热容，从而强化流体的对流传热。相变粒子通常是 采用高分子材料作为外壳，通过聚合反应将相变材料包裹在壳体内，相变材料称为芯体[1-2] 。 Wang 等[3]将粒径为 10 µm 的微胶囊相