淀粉接枝共聚微球对Cd2+的吸附性能研究.pdfVIP

※基础研究 食品科学 2009, Vol. 30, No. 01 31 1 1 2 2 2 2 宁青菊 ，肖昊江 ，李仲谨 ，王 磊 ，朱 雷 ，余丽丽 (1. 陕西科技大学材料科学与工程学院，陕西西安 710021 ；2. 陕西科技大学化学与化工学院，陕西西安 710021) ：在反相悬浮体系中以K2 S2O8-NaHSO3 引发N,N- 亚甲基双丙烯酰胺与淀粉的接枝共聚，制备淀粉接枝共聚 物微球，研究微球对Cd2+ 的吸附行为，利用红外、SEM 、X 射线衍射仪和综合热分析仪对微球及其吸附产物进 行表征，研究吸附机理。结果表明：微球对Cd2+ 吸附行为符合Langmiur 方程和Freundlich 方程；吸附Cd2+ 使微球 的结晶结构被进一步破坏，结晶度下降，同时促进了微球中主链断裂。 ：淀粉接枝共聚微球；吸附；C d 2 + ；机理 Study on Adsorption Behavior of Starch Graft Copolymer Microspheres to Cadmium Ions 1 1 2 2 2 2 NING Qing-ju ，XIAO Hao-jiang ，LI Zhong-jin ，WANG Lei ，ZHU Lei ，YU Li-li (1.College of Materials Science and Engineering, Shaanxi University of Science and Technology, Xi an 710021, China； 2.College of Chemistry and Chemical Engineering, Shaanxi University of Science and Technology, Xian 710021, China) Abstract ：Starch graft copolymer microspheres were synthesized by inverse suspension polymerization with N,N- methylenebisacrylamide and soluble starch, using K2 S2O8-NaHSO3 as initiator. The adsorption behavior of starch graft copolymer microspheres to Cd2+ was investigated. The starch graft copolymer microspheres and their adsorption products were characterized with scan electron microscope (SEM), FT-IR spectroscopy, X-ray diffraction (XRD), and thermogravimetric analysis (TGA). The results showed that the adsorption behavior of the copolymer microspheres to Cd2+ is adapted to Langmiur and Freundlich adsorption isotherm equation. Furthermore, the adsorption of Cd2+ on microspheres not only decreases their crystallinity but promotes the rupture of bonds among their main chains. Key words