GCMS_MS+同时测定鱼样中39+种多溴联苯醚.pdfVIP

4 4 Vol. 4 No. 4 2013 8 Journal of Food Safety and Quality Aug. , 2013 GC-MS/MS 39 1 1 1 1 2 1* 卢大胜 , 林元杰 , 冯 超 , 熊丽蓓 , 金 颖 , 汪国权 (1. , 200336; 2. , 200444) 摘 要: 目的 (ASE)[SPE, (D-SPE) SPE ] GC-MS/MS, 39 (PBDEs)方法 ( 11%)ASE , D-SPE SPE , GC-MS/MS , 结果 (MDLs)0.16~3.29 pg/g; (R20.998)( BDE30 53%, 62%~139%)(RSD20%); , (GC-HRMS)结论 PBDEs , PBDEs 关键词: GC-MS/MS; ; ; ; Determination of 39 polybrominated biphenyl ethers in fish using GC-MS/MS 1 1 1 1 2 1* LU Da-Sheng , LIN Yuan-Jie , FENG Chao , XIONG Li-Bei , JIN Ying , WANG Guo-Quan (1. Shanghai Municipal Center for Disease Control and Prevention, Shanghai 200336 China; 2. School of Life Science, Shanghai University, Shanghai, 200444 China) ABSTRACT: Objective To develop a method to simultaneously determine the 39 polybrominated biphenyl ethers (PBDEs) in fish based on the sample pretreatment of accelerated solvent extraction (ASE) and sequential solid phase extraction (including D-SPE and tandem SPE cartridges) as well as chromatographic separation and detection of GC-MS/MS. Methods After frozen to dry, weever sample (11% of fat content) was treated se- quentially with ASE extraction, D-SPE defatting and t