添加Nd、Zn、Ti的Mg2Ni基合金微观组织及氢化动力学.pdfVIP

Trans. Nonferrous Met. Soc. China 23(2013) 3677−3684 Microstructure and hydrogenation kinetics of Mg Ni-based alloys with addition of Nd, Zn and Ti 2 Wen-jie SONG, Jin-shan LI, Tie-bang ZHANG, Xiao-jiang HOU, Hong-chao KOU, Xiang-yi XUE, Rui HU State Key Laboratory of Solidification Processing, Northwestern Polytechnical University, Xi’an 710072, China Received 29 September 2012; accepted 15 January 2013 Abstract: In order to enhance the hydrogen absorption kinetics of the Mg Ni-based alloys, metal elements (Nd, Zn, and Ti) were 2 added during melting process, respectively. The Mg2Ni-based alloys were melted using an electric resistance furnace under the protection of the covering reagent to prevent the oxidation and the evaporation of magnesium. Phase compositions and microstructures of as-cast alloys were characterized by XRD and SEM equipped with EDS. Hydrogenation kinetics of experimental alloys were investigated by the constant volume method using a Sievert-type apparatus. The addition of Nd, Zn or Ti elements to Mg Ni results in the formation of minor phases Mg Ni and Ni Ti. Nd and Zn are dissolved in α-Mg, Mg Ni and MgNi phases in 2 6 3 2 2 Mg Ni-based alloys. With the addition of Nd, the hydrogen content of the first absorption is 2.86% in mass fraction, which is higher 2 than that of the Mg Ni. Hydrogen absorption kinetics and activation properties of Mg Ni-based alloys are improved evident